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Preparation and formation mechanism of microporous spheric zinc phosphate

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Abstract

In this paper, we investigate the formation of microporous spheric zinc phosphate by anodization method. Zinc phosphate microporous spheres with diameters of 5–23 μm were prepared in H3PO4 and NH4H2PO4 aqueous electrolyte when the applied voltage was 1 V. Microstructure was characterized by scanning electron microscopy. Composition and crystal structure were confirmed through energy dispersive spectrum and X-ray diffraction analysis. The formation mechanism of this special structure was also discussed in this paper.

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Acknowledgments

This work was supported by National Natural Science Foundation of China (No. 50972036) and Support Program for Hundred Excellent Innovation Talents from the Universities and Colleges of Hebei Province.

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Authors and Affiliations

  1. School of Material Science and Engineering, Hebei University of Technology, Tianjin, 300130, People’s Republic of China

    Jianling Zhao, Yongai Sun, Jijing Liu & Chengchun Tang

  2. School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, People’s Republic of China

    Xixin Wang

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  1. Jianling Zhao
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  2. Xixin Wang
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  3. Yongai Sun
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  4. Jijing Liu
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Correspondence to Jianling Zhao.

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Zhao, J., Wang, X., Sun, Y. et al. Preparation and formation mechanism of microporous spheric zinc phosphate. J Solid State Electrochem 15, 1861–1865 (2011). https://doi.org/10.1007/s10008-010-1202-x

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  • DOI: https://doi.org/10.1007/s10008-010-1202-x

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