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Characterization of strontium and barium manganates by abrasive stripping voltammetry

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Abstract

Abrasive stripping voltammetry is applied in order to characterize barium and strontium manganates-(V) and -(VI) in solid state phases. Voltammetric reduction peak potential values of KBaMnO4, Ba3(MnO4)2, Ba3(MnO4)2− x (BO3) x (x=0.031(1)), Ba5(MnO4)3OH, Ba5(MnO4)3Cl, Sr5(MnO4)3OH and BaMnO4 are shown to be proportional to the corresponding average Mn-O distances, which were determined from X-ray powder diffractometric data through Rietveld refinement analyses.

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Authors and Affiliations

  1. Institut für chemische Technologie anorganischer Stoffe, Technische Universität Graz, Stremayrgasse 16/III, A-8010 Graz, Austria Tel.: +43-316-873 8763, Fax: +43-316-873 8272, e-mail: f537albe@mbox.tu-graz.ac.at, , , , , , AT

    Dirk A. Fiedler, Jörg H. Albering & Jürgen O. Besenhard

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  1. Dirk A. Fiedler
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  2. Jörg H. Albering
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  3. Jürgen O. Besenhard
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Received: 25 November 1997 / Accepted: 28 January 1998

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Fiedler, D., Albering, J. & Besenhard, J. Characterization of strontium and barium manganates by abrasive stripping voltammetry. J Solid State Electrochem 2, 413–419 (1998). https://doi.org/10.1007/s100080050119

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  • DOI: https://doi.org/10.1007/s100080050119

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