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Fast atom bombardment mass spectrometry of pertechnetate

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Abstract

Negative Ion Fast Atom Bombardment Mass Spectrometry is conducted on potassium pertechnetate evaporated onto a copper probe. The mass spectra of pertechnetate /TcO −4 / reveal the presence of mononuclear and polynuclear technetium oxo species which form general series TcnO −n+1 ,...TcnOn+4 with n=1 to 5. The polynuclear species are believed to be formed via gas phase reactions.

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Author notes

  1. T. C. Pinkerton

    Present address: Forensic Science Research Group, Federal Bureau of Investigation, FBI Academy, 22135, Quantico, VA, USA

Authors and Affiliations

  1. Department of Chemistry, Purdue University, 47907, West Lafayette, Indiana, USA

    B. L. Lawson, D. J. Hoch & T. C. Pinkerton

  2. Department of Medicinal Chemistry, Purdue University, 47907, West Lafayette, Indiana, USA

    D. D. Fetterolf

Authors
  1. D. D. Fetterolf
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  2. B. L. Lawson
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  3. D. J. Hoch
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  4. T. C. Pinkerton
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Fetterolf, D.D., Lawson, B.L., Hoch, D.J. et al. Fast atom bombardment mass spectrometry of pertechnetate. Journal of Radioanalytical and Nuclear Chemistry Letters 94, 63–70 (1985). https://doi.org/10.1007/BF02199554

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  • DOI: https://doi.org/10.1007/BF02199554

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