Abstract
The activation energy spectrum model can be used quite successfully to explain various aspects of the kinetics of structural relaxation in metallic glasses. In order to describe the often observed reversible component in a more quantitative way in the framework of this model an expression for the temperature dependence of the reversible part of the activation energy spectrum is derived. Using this expression three experiments concerning the reversible enthalpy change during structural relaxation are simulated and the results are compared with the actual experimental traces.
Similar content being viewed by others
References
W. Primak,Phys. Rev. 100 (1955) 1677.
M. R. J. Gibbs, J. E. Evetts andJ. A. Leake,J. Mater. Sci. 18 (1983) 278.
J. A. Leake, M. R. J. Gibbs, S. Vryenhoef andJ. E. Evetts, inJ. Non-Cryst. Solids 61&62 (1984) 787.
H. Kronmüller,Phil. Mag. 48 (1983) 127.
J. E. Evetts, in Proceedings of the 5th International Conference on Rapidly Quenched Metals, Würzburg, FRG September 1984, edited by S. Steeb and H. Warlimont (North Holland Physics Publishing, Amsterdam, 1985) p. 607.
I. N. Bronstein andK. A. Semendjajew, in “Taschenbuch der Mathematik”, (Verlag Harry Deutsch, Frankfurt, 1980) p. 118.
G. Hygate andM. R. J. Gibbs,J. Phys. F 17 (1987) 815.
F. Sommer, H. Haas andB. Predel, in Proceedings of the 5th International Conference on Rapidly Quenched Metals, Würzburg, FRG, September 1984, edited by S. Steeb and H. Warlimont (North Holland Physics Publishing, Amsterdam, 1985) p. 627.
F. Sommer, H. Haas andB. Predel,J. Non-Cryst. Solids 61&62 (1984) 793.
Ch. Görlitz andH. Ruppersberg, in Proceedings of the 5th International Conference on Rapidly Quenched Metals, Würzburg, FRG, September 1984, edited by S. Steeb and H. Warlimont (North Holland Physics Publishing, Amsterdam, 1985) p. 631.
Ch. Görlitz, Private communication.
I. Majewska-Glabus andB. J. Thibjsse, in Proceedings of the 5th International Conference on Rapidly Quenched Metals, Würzburg, FRG, September 1984, edited by S. Steeb and H. Warlimont (North Holland Physics Publishing, Amsterdam, 1985) p. 635.
T. Egami, In Proceedings of the 5th International Conference on Rapidly Quenched Metals, Würzburg, FRG, September 1984, edited by S. Steeb and H. Warlimont (North Holland Physics Publishing, Amsterdam, 1985) p. 611.
J. Horvath, K. Freitag andH. Mehrer, in Proceedings of the 5th International Conference on Rapidly Quenched Metals, Würzburg, FRG, September 1984, edited by S. Steeb and H. Warlimont (North Holland Physics Publishing, Amsterdam, 1985) p. 751.
A. Inoue, T. Masumoto andH. S. Chen,J. Mater. Sci. 19 (1984) 3953.
J. W. Drijver, A. L. Mulder andS. Radelaar, in Proceedings of the 4th International Conference on Rapidly Quenched Metals, Sendai, Japan, August 1981, edited by T. Masumoto and K. Suzuki, (The Japan Institute of Metals, Aoba Aramki, Sendai 980, Japan, 1982) p. 535.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Woldt, E. The reversible enthalpy change of the metallic glass Fe40Ni40B20 — Experiments and simulation in the activation energy spectrum model. J Mater Sci 23, 4383–4391 (1988). https://doi.org/10.1007/BF00551936
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00551936