Abstract
The effect of grain size on the martensitic transformation in Ni42Ti shape memory alloy has been studied. The kinetics of grain growth has been evaluated and the influence of different grain sizes on the transformation temperatures and the thermodynamic magnitudes has been reported. Image analysis and flow calorimetry techniques have been used. The study shows that grain boundaries favour the martensitic transformation and at the same time obstruct retransformation. Enthalpy and entropy variations are independent of grain size, but elastic energy decreases with the grain size.
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F. J. Gil, PhD thesis, Universidad de Barcelona (1989).
J. Muntasell, J. L. Tamarit, E. Cesari, J. M. Guilemany and F. J. Gil, Mater. Res. Bull. 24 (1989) 445.
P. J. Brofman and G. S. Ansell, Metall. Trans. 14A (1983) 1929.
S. Kajiwara, ibid. 17A (1986) 1693.
P. A. Beck, J. C. Kremer, L. S. Demer and M. L. Holzworth, Trans. Met. Soc. AIME 175 (1948) 507.
P. A. Beck, J. Appl. Phys. 19 (1948) 507.
P. A. Beck, J. Towers and W. O. Manley, Trans. Met. Soc. AIME 185 (1951) 634.
G. T. Higgins, Met. Sci. 8 (1974) 143.
B. Ralph, Mater. Sci. Technol. 6 (1990) 1139.
J. Ortín and A. Planes, Acta Metall. 36 (1988) 1873.
J. M. Guilemany and F. J. Gil, Mater. Res. Bull. 25 (1990) 1352.
A. G. Guy and J. J. Hren, “Elements of Physical Metallurgy”, 3rd edn (Addison-Wesley, Massachusetts, 1974) p. 446.
D. N. Adnyana, in “Proceedings of the International Conference on Martensitic Transformation, ICOMAT-86” (The Japan Institute of Metals, Naru, 1986) p. 774.
C. M. Wayman and H. C. Tong, Scripta Metall. 11 (1977) 341.
H. C. Tong and C. M. Wayman, Acta Metall. 22 (1974) 887.
M. Hillert, ibid. 13 (1965) 227.
G. T. Higgins, Met. Sci. 8 (1974) 143.
R. Elst, J. Van Humbeeck and L. Delaey, Z. Metallkde 76 (1985) 705.
K. Shimizu and T. Tadaki, in “Shape Memory Alloys”, edited by H. Funakubo (Gordon & Breach, Tokyo, 1984) p. 19.
D. Koskimaki, M. J. Marcinkowski and A. S. Sastri, Trans. Met. Soc. AIME 245 (1969) 1883.
J. M. Guilemany and F. J. Gil, J. Mater. Sci. 26 (1991) 4626.
R. L. Fulhman, “Interfaces Seminar” (American Society for Metals, Metals Park, OH, 1952) p. 179.
F. J. Gil and J. A. Planell, Scripta Metall. Mater. 25 (1991) 2843.
J. M. Guilemany and F. J. Gil, Thermochim. Acta 167 (1990) 136.
Idem, J. Mater. Sci. 9 (1974) 1545.
Idem, J. Mater. Sci. Lett. 12 (1993) 6.
J. Ortín and A. Planes, Acta Metall. 36 (1988) 1873.
C. M. Friend, J. Ortín, L. Mañosa and M. Yoshikawa. Scripta. Metall. Mater. 24 (1990) 1641.
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Gil, F.J., Manero, J.M. & Planell, J.A. Effect of grain size on the martensitic transformation in NiTi alloy. J Mater Sci 30, 2526–2530 (1995). https://doi.org/10.1007/BF00362129
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DOI: https://doi.org/10.1007/BF00362129