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Xenon 5p–4d cascade emission upon 3d-photoionization

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Abstract

We investigated the photon-emission spectrum of Xe atoms upon photoionization of the Xe 3d-subshell. The 5p-4d spectrum is emitted in the process of the cascading decay of the 3d-vacancy and has a complex multi-component structure reflecting a great number of transitions from various ionic configurations produced during the cascade development. The spectrum is assigned by the direct construction of the cascade de-excitation tree. 21 different transitions between configurations of multiply charged Xe ions (+2 to +6) are found to be contributing to the spectrum. The 5p-4d partial fluorescence yield is found to be six times greater for the 3d-ionization than for the 4d-ionization. The effect of the multiplet splitting in the initial and final states of the emitting transitions is studied.

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Correspondence to A. G. Kochur.

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Kochur, A., Brühl, S., Petrov, I. et al. Xenon 5p–4d cascade emission upon 3d-photoionization. Eur. Phys. J. Spec. Top. 169, 51–58 (2009). https://doi.org/10.1140/epjst/e2009-00972-1

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