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Investigation of aromatic hydrocarbon inclusion into cyclodextrins by Raman spectroscopy and thermal analysis

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Abstract

Among various cavitand molecules, cyclodextrins are extensively studied due to their ability to form host-guest complexes with small hydrophobic molecules. Aiming to explore cyclodextrin implementation on the scopes related to the environmental pollution monitoring or remediation, extensive studies for understanding the cyclodextrin-based host-guest complex formation with selected targeted substances are conducted. In this context, two polycyclic aromatic hydrocarbons, naphthalene and fluoranthene as well as toluene as a member of volatile organic compounds, were studied regarding their ability to encapsulate into cyclodextrin cavities. Synthesised complexes were examined by thermogravimetric analysis combined with Raman spectroscopy. The obtained results demonstrated that the size between targeted molecules and the cyclodextrin cavities strongly correlates with its ability to engage in complexation. Thus, this latter parameter plays an important role in the inclusion complex formation as well as in the strength of the interaction between the molecules.

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Acknowledgments

The authors would like to acknowledge the Remantas project (ANR-11-ECOT-0010), supported by French National Research Agency (ANR) for a financial support.

Conflict of interest

The authors declare no conflict of interest.

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Authors and Affiliations

  1. Laboratoire CSPBAT UMR CNRS 7244, UFR Santé Médecine Biologie Humaine, Université Paris 13, 74 rue Marcel Cachin, 93017, Bobigny, France

    Inga Tijunelyte, Nathalie Dupont, Irena Milosevic, Carole Barbey, Nathalie Lidgi-Guigui, Erwann Guenin & Marc Lamy de la Chapelle

  2. IFREMER, Laboratoire Détection, Capteurs et Mesures, Unité Recherches et Développements Technologiques, CS10070, 29280, Plouzané, France

    Emmanuel Rinnert

Authors
  1. Inga Tijunelyte
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  2. Nathalie Dupont
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  3. Irena Milosevic
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  4. Carole Barbey
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  5. Emmanuel Rinnert
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  6. Nathalie Lidgi-Guigui
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  7. Erwann Guenin
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Correspondence to Marc Lamy de la Chapelle.

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Tijunelyte, I., Dupont, N., Milosevic, I. et al. Investigation of aromatic hydrocarbon inclusion into cyclodextrins by Raman spectroscopy and thermal analysis. Environ Sci Pollut Res 24, 27077–27089 (2017). https://doi.org/10.1007/s11356-015-4361-6

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  • DOI: https://doi.org/10.1007/s11356-015-4361-6

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