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Stratigraphy of nutrients and metals in sediment profiles of two dimictic lakes in North-Eastern Germany

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Environmental Geology

Abstract

A sedimentological study of two dimitic lakes in North-Eastern Germany provided a record of anthropogenic impacts and historical changes of water quality. The upper 50 cm sediment profiles were compared for major nutrients and selected major trace elements. The sediments were dated by 210Pb and 137Cs measurement. The upper 50 cm sediment profiles represent approximately the last 100 years of history in both lakes. Element analyses show different characteristic stratigraphic patterns in both lakes. Based on the nutrient and metal stratification, three characteristic time periods can be documented for both lakes. In addition to agricultural use of the catchment area, atmospheric pollution greatly influenced the metal concentration in the sediment layers. Variation in the external loading and redox conditions in the hypolimnion explain the variation in the composition and accumulation of metals in the sediment stratigraphy. No increases or changes in the trophic level of either lake could be documented based on the accumulation of the nutrients C, N and P. The ratio of Fe/Mn and Fe/Ca characterized the changing redox conditions. The stratigraphy of Pb and Zn agrees with the historical variation in atmospheric pollution and confirms literature values for Central and North Europe. The drop in Pb and Zn over the last 10–15 years is a regional effect in North-Eastern Germany.

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References

  • Abril JM (2003) Difficulties in interpreting fast mixing in the radiometric dating of sediments using 210Pb and 137CS. J Paleolim 30:407–414

    Article  Google Scholar 

  • Appleby PG, Oldfield F (1983) The assessment of 210Pb dates from sites with varying sediment accumulation rates. Hydrobiol 103:29–35

    Article  Google Scholar 

  • Appleby PG, Richardson N, Nolan PJ (1992) Self-absorption corrections for well-type germanium detectors. Nucl Instr and Methods 71:228–233

    Article  Google Scholar 

  • Bengston L, Persson T (1978) Sediment changes in a lake used for sewage reception. Polskie Arch Hydrobiol 25:17–33

    Google Scholar 

  • Bennion H, Wunsam S, Schmidt R (1995) The validation of diatom-phosphorus transfer functions: an example from Mondsee, Austria. Freshwat Biol 34:271–283

    Article  Google Scholar 

  • Bostroem B, Andersen JM, Fleischer S, Jansson M (1988) Exchange of phosphorus across the sediment-water interface. Hydrobiol 170:229–244

    Google Scholar 

  • Dixit SS, Dixit AS, Smol JP (2000) Water quality changes from human activities in three Northestern USA lakes. Lake Reserv Manage 16(4):305–321

    Article  Google Scholar 

  • Dreßler M, Selig U, Dörfler W, Adler S, Schubert H, Hübener T (2006) Environmental changes and the migration period in northern Germany as reflected in the sediments of Lake Dudinghausen. Quaternary Res 66:25–37

    Article  Google Scholar 

  • Dreßler M, Hübener T, Goers S, Werner P, Selig U (2007) Multi-proxy reconstruction of trophic state, hypolimnetic anoxia and phototrophic sulphur bacteria abundance in a dimictic lake in Northern Germany over the past 80 years. J Paleolim 37(2):205–219

    Article  Google Scholar 

  • Einsele W (1936) Über die Beziehung des Eisenkreislaufes zum Phosphorkreislauf in eutrophen See. Arch Hydrobiol 29:664–684

    Google Scholar 

  • Engstrom DR, Wright Jr HE (1984) Chemical stratigraphy of lake sediments as a record of environmental change. In: Lund JWG (ed) Lake sediments and environmental history. Haworth, EY, pp 11–67

    Google Scholar 

  • Gallagher L, MacDonald RW, Paton DW (2004) The historical record of metals in sediments from six lakes in the fraser river basin, British Columbia. Water Air Soil Pollut 152:257–278

    Article  Google Scholar 

  • Garrison PJ, Wakeman RS (2000) Use of paleolimnology to document the effect of lake shoreland development on water quality. J Paleolim 24:369–393

    Article  Google Scholar 

  • Goslar T, Ralska-Jasiewiczowa M, van Geel B, Lacka B, Szeroczynka K, Chrost L, Walanus A (1999) Anthropogenic changes in the sediment composition of Lake Gosciaz (central Poland), during the last 330 yrs. J Paleolim 22:171–185

    Article  Google Scholar 

  • Hongve D (2003) Chemical stratigraphy of recent sediments from a depth gradient in a meromictic lake, Nordbytjernet, SE Norway, in relation to variable external loading and sedimentary fluxes. J Paleolim 30:75–93

    Article  Google Scholar 

  • Itkonen A, Marttila V, Meriläinen JJ, Salonenv P (1999) 8000—year history of palaeoproductivity in a large boreal lake. J Paleolim 21:271–294

    Article  Google Scholar 

  • Kemp ALW, Thomas RL, Dell CI, Jaquet JM (1976) Cultural impact on geochemistry of sediments in Lake Erie. J Fish Res Board Can 33(3):440–462

    Google Scholar 

  • Kenney WF, Schelske CL, Chapman AD (2001) Changes in polyphosphate sedimentation: a response to excessive phosphorus enrichment in a hypereutrophic lake. Can J Fish Aquat Sci 58:879–887

    Article  Google Scholar 

  • Koinig KA, Shotyk W, Lotter AF, Ohlendorf C, Sturm M (2003) 9000 years of geochemical evolution of lithogenic major and trace elements in the sediment of an alpine lake—the role of climate, vegetation, and land-use history. J Paleolim 30:307–320

    Article  Google Scholar 

  • Löffler H (1986) An early meromictic stage in Lobsigensee (Switzerland) as evidenced by ostracods and Chaoborus. Hydrobiol 143:309–314

    Article  Google Scholar 

  • Loizeau JL, Span D, Coppee V, Dominik J (2001) Evolution of the trophic state of Lake Annecy (eastern France) since the last glaciation as indicated by iron, manganese and phosphorus speciation. J Paleolim 25:205–214

    Article  Google Scholar 

  • Lotter AF (2001) The paleolimnology of Soppensee (Central Switzerland), as evidenced by diatom, pollen, and fossil-pigment analyses. J Paleolim 25:65–79

    Article  Google Scholar 

  • Neumann T, Christiansen C, Clasen S, Emeis KC, Kunzendorf H (1997) Geochemical records of salt-water inflows into the deep basin of the Baltic Sea. Cont Shelf Res 17(1):95–115

    Article  Google Scholar 

  • OECD (1982) Eutrophications of waters. Monitoring, assessment and control. OECD report, OECD Paris, 154 pp

  • Olsson S, Regnell J, Persson A, Sandgren P (1997) Sediment-chemistry response to land-use change and pollutant loading in a hypertrophic lake, southern Sweden. J Paleolim 17:275–294

    Article  Google Scholar 

  • Penn MR, Auer MT, Van Orman EL, Korienek JJ (1995) Phosphorus diagenesis in lake sediments: investigations using fractionation techniques. Mar Freshwater Res 46:89–99

    Google Scholar 

  • Psenner R, Pucsko R, Sager M (1984) Die Fraktionierung organischer und anorganischer Phosphorbindungen von Sedimenten–Versuch einer Definition ökologisch wichtiger Fraktionen. Arch Hydrobiol Suppl 70:111–155

    Google Scholar 

  • Rippey B (1990) Sediment chemistry and atmospheric contamination. Philos Trans R Soc Lond B 327:311–317

    Article  Google Scholar 

  • Schaller T, Moor HC, Wehrli B (1997) Sedimentary profiles of Fe, Mn, V, Cr, As and Mo recording signals of changing deep-water oxygen conditions in Baldeggersee. Aquat Sci 59:345–361

    Article  Google Scholar 

  • Scharf BW (1998) Eutrophication history of Lake Arendsee (Germany). Palaeogeograph Palaeo-climatol Palaeoecol 140:85–96

    Article  Google Scholar 

  • Selig U, Schlungbaum G (2003) Characterisation and quantification of phosphorus release from profundal bottom sediments in two dimictic lakes during summer stratification. J Limnol 62(2):151–162

    Google Scholar 

  • Selig U, Hübener T, Schwarz A, Leipe T (2002) The environmental history investigations of a postglacial dimictic lake in North Germany. Proc Int Assoc Limnol 28:1340–1344

    Google Scholar 

  • Selig U, Hübener T, Heerkloss R, Schubert H (2004) Vertical gradient of nutrients in two dimictic lakes—influence of phototrophic sulfur bacteria on the nutrient balance. Aquat Sci 66(3):247–256

    Google Scholar 

  • Selig U, Fischer K, Leipe T (2005) Phosphorus accumulation in lake sediments during the last 14,000 years: description by fractionation techniques and X-ray micro analysis. J Freshwater Ecol 20(2):347–359

    Google Scholar 

  • Ter Braak CJF, Van Dam H (1989) Inferring pH from diatoms: a comparison of old and new calibration methods. Hydrobiol 178:209–223

    Article  Google Scholar 

  • Verardo DJ, Froelich PN, McIntyre A (1990) Determination of organic carbon and nitrogen in marine sediments using the Carlo Erba NA-1500 Analyser. Deep Sea Res 37:157–165

    Article  Google Scholar 

  • Walker IR, Levesque AJ, Cwynar LC, Lotter AF (1997) An expanded surface-water palaeotemperature inference model for use with fossil midges from eastern Canada. J Paleolim 18:165–178

    Article  Google Scholar 

Download references

Acknowledgments

We gratefully thank Dr. Helmut Erlenkeuser, Leibniz Laboratory for Radiometric Research of the University Kiel, for analysis of 210Pb and 137CS activity profiles. The Ministry of Environmental Mecklenburg-Vorpommern, Germany, supported this study.

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Correspondence to Uwe Selig.

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Selig, U., Leipe, T. Stratigraphy of nutrients and metals in sediment profiles of two dimictic lakes in North-Eastern Germany. Environ Geol 55, 1099–1107 (2008). https://doi.org/10.1007/s00254-007-1058-2

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