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Perovskite-like fluorides and oxyfluorides: Phase transitions and caloric effects

  • Dedicated to the Memory of K.S. Aleksandrov
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Abstract

An analysis of the effect that chemical and hydrostatic pressures have on the thermodynamic properties of perovskite-like fluorine-oxygen compounds A 2 A′MeO x F6 − x has revealed that materials under-going order-disorder transitions and having significant external-pressure compliance have the highest caloric efficiency. Some of the fluorides and oxyfluorides under study can be considered promising solid coolants.

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Authors and Affiliations

  1. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russia

    I. N. Flerov & M. V. Gorev

  2. Institute of Engineering Physics, Siberian Federal University, Krasnoyarsk, 660074, Russia

    I. N. Flerov & M. V. Gorev

  3. Institut de Chimie de la Matiere Condensee, CNRS, 33608, Pessac Cedex, France

    A. Tressaud

  4. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, 690022, Russia

    N. M. Laptash

Authors
  1. I. N. Flerov
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  2. M. V. Gorev
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  3. A. Tressaud
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  4. N. M. Laptash
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Correspondence to I. N. Flerov.

Additional information

Original Russian Text © I.N. Flerov, M.V. Gorev, A. Tressaud, N.M. Laptash, 2011, published in Kristallografiya, 2011, Vol. 56, No. 1, pp. 13–21.

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Flerov, I.N., Gorev, M.V., Tressaud, A. et al. Perovskite-like fluorides and oxyfluorides: Phase transitions and caloric effects. Crystallogr. Rep. 56, 9–17 (2011). https://doi.org/10.1134/S106377451101010X

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  • DOI: https://doi.org/10.1134/S106377451101010X

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