Skip to main content
SpringerLink
Log in

Kinetic model of the medium for formation of combustible nitrogen oxides in a coal-dust flare

  • Published:
Combustion, Explosion and Shock Waves Aims and scope

Abstract

A kinetic model of the medium (least complicated kinetic mechanism) is constructed for the formation of combustible nitrogen oxides in coal-dust flares. The model includes both the yield kinetics of volatiles from the coal with formation of a fuel gas mixture and the chemical reaction kinetics in the gaseous phase, which describe the conversion of nitrogen-containing components into NO during the combustion of the volatiles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. A. Levitskii, S. A. Losev, and V. N. Makarov, “Chemical kinetics problems in the AVOGADRO automated scientific research system,” in:Mathematical Models in Chemical Kinetics [in Russian], Nauka, Novosibirsk (1990), pp. 7–38.

    Google Scholar 

  2. G. Ya. Gerasimov and V. N. Makarov, “Analysis of the mechanism, for a complex chemical reaction with radiation-chemical decontamination of gases as an example,”Khim. Fiz.,16, No. 1, 89–99 (1997).

    Google Scholar 

  3. P. V. Roslyakov, “Calculating the formation of nitrogen oxides during combustion of nitrogen-containing fuels,”Teploénergetika, No. 1, 37–41 (1986).

    Google Scholar 

  4. Y. H. Song, D. W. Blair, V. J. Siminski, and W. Bartok, “Conversion of fixed nitrogen to N2 in rich combustion,” in:Proc. 18th Symp. (Int.) on Combustion, The Combustion Inst. (1981), pp. 53–63.

  5. V. I. Babii and Yu. F. Kuvaev,Burning of Coal Dust and the Design of Coal-Dust Flares [in Russian], Energoatomizdat, Moscow (1986).

    Google Scholar 

  6. P. H. Solomon and D. G. Hamblen, “Pyrolysis,” in: R. H. Schlosberg (ed.),Chemistry of Coal Conversion, Plenum Press, New York, (1985), pp. 121–252.

    Google Scholar 

  7. P. K. Agarwal, J. B. Agnew, N. Ravindran, and R. Weimann, “Distributed kinetic parameters for evolution of gaseous species in the pyrolysis of coal,”Fuel,66, 1097–1106 (1987).

    Article  Google Scholar 

  8. A. Attar and G. G. Hendrickson, “Functional groups and heteroatoms in coal,” in: R. A. Meyers (ed.),Coal Structure, New York (1982), pp. 131–198.

  9. G. H. Ko, W. A. Peters and J. B. Howard, “Correlation of tar yields from rapid pyrolysis with coal type and pressure,”Fuel,66, 1118–1122 (1987).

    Article  Google Scholar 

  10. N. J. Pitz and C. K. Westbrook, “A comprehensive chemical kinetic reaction mechanism for the oxidation ofn-butane,” in:Proc. 20th Symp. (Int.) on Combustion, The Combustion Inst. (1984), pp. 831–843.

  11. D. S. Y. Hsu, C. Y. Lin, and M. C. Lin, “CO formation in the early stage of high temperature benzene oxidation under fuel lean conditions: Kinetics of the initiation reaction C6H6→C6H5+H,”ibid., Proc 20th Symp. (Int.) on Combustion, The Combustion Inst. (1984), pp. 623–630.

  12. W. A. Hahn and J. O. L. Wendt, “NOx formation in flat, laminar, opposed jet methane diffusion flames,” in:Proc. 18th Symp. (Int.) on Combustion, The Combustion Inst. (1981), pp. 121–131.

  13. M. F. Zhukov, R. A. Kalinenko, A. A. Levitskii, and L. S. Polak,Plasma Chemical Processing of Coal [in Russian], Nauka, Moscow (1990).

    Google Scholar 

  14. V. G. Kashirskii, “Production of benzene hydrocarbons and thiophene by rapid pyrolysis of solid fuels,”Khim. Tverd. Tela, No. 4, pp. 70–72 (1986).

    Google Scholar 

  15. S. P. Titov, V. I. Babii, and V. M. Barabash, “Study of NO formation from nitrogen in fuel during combustion of coal dust,”Teploénergetika, No. 3, 64–67 (1980).

    Google Scholar 

  16. W. Tsang and J. T. Herron, “Chemical kinetic data base for propellant combustion. I. Reactions involving NO, NO2, HNO, HNO2, HCN, and N2O,”J. Phys. Chem. Ref. Data,20, 609–663 (1991).

    Article  ADS  Google Scholar 

  17. W. Tsang, “Chemical kinetic data base for propellant combustion. II. Reactions involving CN, NCO, and HNCO,”J. Phys. Chem. Ref. Data,21, 752–791 (1991).

    Google Scholar 

  18. É. P. Volkov, L. I. Zaichik, and V. A. Pershukov,Modelling the Combustion of Solid Fuels [in Russian], Nauka, Moscow (1994).

    Google Scholar 

  19. P. J. Smith, S. C. Hill, and L. D. Smoot., “Theory for NO formation in turbulent coal flames,” in:Proc. 19th Symp. (Int.) on Combustion, The Combustion Inst. (1982), pp. 1263–1270.

  20. G. Ya. Gerasimov, S. A. Losev, and V. N. Makarov, “The AVOGADRO program: Ecological problems in thermal power production,”Inzh.-Fiz. Zh.,69, No. 6, 921–926 (1996).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Mechanics, Moscow State University, 119899, Moscow

    V. N. Makarov & G. Ya. Gerasimov

Authors
  1. V. N. Makarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Ya. Gerasimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromFizika Goreniya i Vzryva, Vol. 35, No. 2, pp. 23–29, Mach–April 1999.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makarov, V.N., Gerasimov, G.Y. Kinetic model of the medium for formation of combustible nitrogen oxides in a coal-dust flare. Combust Explos Shock Waves 35, 133–138 (1999). https://doi.org/10.1007/BF02674425

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02674425

Keywords

Search

Navigation