Summary
Seven aromatic and alkyl amylose and cellulose carbamates have been tested as chiral stationary phases in gas chromatography. One of them, amylose tris(n-butylcarbamate) can be used for enantiomer separation.
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References
V. Schurig, H.-P. Nowotny, M. Schleimer, D. Schmalzing, J. High Res. Chromatogr. & Chromatogr. Commun.12, 549 (1989).
E. Gil-Av, B. Feibush, R. Charles-Sigler, Tetrahedr. Lett. 1009 (1966).
E. Gil-Av, B. Feibush, Tetrahedr. Lett. 3345 (1967).
H. Frank, G. J. Nicholson, E. Bayer, H. Chromatogr. Sci.15, 174 (1977).
G. J. Nicholson, H. Frank, E. Bayer, J. High Res. Chromatogr. & Chromatogr. Commun.2, 411 (1979).
V. Schurig, Angew. Chem.96, 733 (1984); Angew. Chem. Int. Ed. Engl.23, 747 (1984).
R. H. Liu, W. W. Ku, J. Chromatogr.271, 309 (1983).
W. A. König, The Practice of Enantiomer Separation by Capillary Gas Chromatography, Hüthig, Heidelberg (1987).
V. Schurig, Angew. Chem.89, 113 (1977); Angew. Chem. Int. Ed. Engl.16, 110 (1977).
V. Schurig, Chromatographia13, 263 (1980).
V. Schurig, H.-P. Nowotny, D. Schmalzing, Angew. Chem.101, 785 (1989); Angew. Chem. Int. Ed. Engl.28, 736 (1989).
V. Schurig, H.-P. Nowotny, Angew. Chem.102, 969 (1990); Angew. Chem. Int. Ed. Engl.29, 939 (1990).
Y. Okamoto, M. Kawashima, K. Hatada, J. Chromatogr.363, 173 (1986).
Y. Okamoto, R. Aburatani, T. Fukumoto, K. Hatada, Chemistry Letters, 1857 (1987).
Y. Okamoto, R. Aburatani, S. Miura, K. Hatada, J. Liquid Chromatogr.10, (8 & 9), 1613 (1987).
Y. Okamoto, Y. Kaida, J. High Res. Chromatogr. & Chromatogr. Commun13, 708 (1990).
K. Grob, Making and Manipulating Capillary Columns for Gas Chromatography, Hüthig, Heidelberg (1986), p. 159.
K. Grob, Making and Manipulating Capillary Columns for Gas Chromatography, Hüthig, Heidelberg (1986), p. 212.
D. W. Armstrong, A. M. Stalcup, M. L. Hilton, J. D. Duncan, J. R. Faulkner, Jr., S.-H. Chang, Anal. Chem.62, 1610 (1990).
W. A. König, Carbohydr. Res.192, 51 (1989).
V. Schurig, D. Schmalzing, U. Mühleck, M. Jung, M. Schleimer, P. Mussche, C. Duvekot, J. C. Buyten, J. High Res. Chromatogr. & Chromatogr. Commun.13, 713 (1990).
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Schurig, V., Zhu, J. & Muschalek, V. Enantiomer separation on amylose tris(n-butylcarbamate) by gas chromatography. Chromatographia 35, 237–240 (1993). https://doi.org/10.1007/BF02269709
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DOI: https://doi.org/10.1007/BF02269709