Summary
The retention of benzene derivatives with nonpolar and polar substituents on a porous methacrylate copolymer containing epoxy groups using both nonpolar and polar eluents was investigated. When n-hexane is used as the eluent, the retention of n-alkylbenzenes and polymethylbenzenes is weaker than that of benzene. In the case of benzene derivatives containing polar functional groups their capacity ratios (k) on this porous polymer increases approximately linearly with the increase of the adsorbate molecules dipole moment. The retention characteristics of the methacrylate copolymer were compared with that of a styrene-divinylbenzene copolymer and silica gels with a hydroxylated surface and with a surface modified by chemically bonded alkylsilyl groups.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
F. Švec, Pryskyrice,77, 48 (1977).
O. Mikes, P. Štrop, J. Čoupek, J. Chromatogr.153, 23 (1978).
M. Popl, J. High Resolut. Chromat, and Chromat. Commun1, 225 (1978).
J. Čoupek, M. Popl, Analusis7, 28 (1979).
T. Hanai, Chromatographia12, 77 (1979).
M. Wojaczynska, B. N. Kolarz, J. Chromatogr.196, 75 (1980).
K. Aramoki, T. Hanai, H. F. Walton, Anal. Chem.52, 1963 (1980).
P. Jandera, J. Churaček, J. Caslavsky, D. Szabo, Chromatographia14, 100 (1981).
P. Jandera, J. Churaček, D. Szabo, Chromatographia14, 7 (1981).
J. Kàlal, F. Švec, E. Kálalová, L. Radová, Angew. Makromol. Chem.66, 51 (1978).
A. V. Kiselev, A. Ya. Korolev, R. S. Petrova, K. D. Shcherbakova, Kolloidn. Zhurnal22, 671 (1960).
L. D. Belyakova, A. V. Kiselev, N. P. Platonova, J. Kálal, F. Švec, J. Hradil, Angew. Makromol. Chem.96, 69 (1981).
A. V. Kiselev, Ya. I. Yashin “Adsorbtsionnaya gazovaya i zhidkostnaya khromatografiya” (Adsorption Gas and Liquid Chromatography), Khimiya Press, Moscow, 1979.
A. N. Ageev, A. V. Kiselev, Ya. I. Yashin, Doklady Akad. Nauk SSSR249, 337 (1979).
A. N. Ageev, A. V. Kiselev andYa. I. Yashin, Chromatographia13, 669 (1980).
A. N. Ageev, A. V. Kiselev, Ya. I. Yashin, Chromatographia14, 638 (1981).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ageev, A.N., Aratskova, A.A., Belyakova, L.D. et al. Liquid chromatography of benzene derivatives on a porous methacrylate copolymer containing epoxy groups. Chromatographia 17, 545–548 (1983). https://doi.org/10.1007/BF02261917
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02261917