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Adsorption of silver on cellobiose and cellulose studied with MIES, UPS, XPS and AFM

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Abstract

Metastable induced electron spectroscopy, ultraviolet photoelectron spectroscopy and X-ray photoelectron spectroscopy as well as atomic force microscopy were employed to study the adsorption of silver on cellulose as well as its precursor cellobiose. The formation of silver nanoparticles encapsulated by the organic film previously found for the monomer glucose is well reproduced for the dimer cellobiose. For the polymer cellulose on the other hand, no nanoparticle formation is found even though the surface is covered with silver atoms. No significant chemical interaction is found in any of these cases.

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Acknowledgments

We thankfully acknowledge the provision of the Atomic Force Microscope by the group of Prof. W. Daum (Institut für Energieforschung und Physikalische Technologien, TU Clausthal) as well as the technical assistance of Lienhard Wegewitz and Dana Schulte Genannt Berthold. Finally, we thank the Deutsche Forschungsgemeinschaft (DFG) for financial support under Project Numbers MA 1893/18-1 and VI 359/9-1.

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Authors and Affiliations

  1. Institut für Energieforschung und Physikalische Technologien, Technische Universität Clausthal, Leibnizstrasse 4, 38678, Clausthal-Zellerfeld, Germany

    S. Dahle, J. Meuthen & W. Maus-Friedrichs

  2. Hochschule für Angewandte Wissenschaft und Kunst, Fakultät für Naturwissenschaften und Technik, Von-Ossietzky-Straße 99, 37085, Göttingen, Germany

    S. Dahle & W. Viöl

  3. Anwendungszentrum für Plasma und Photonic APP, Fraunhofer-Institut für Schicht-und Oberflächentechnik IST, Von-Ossietzky-Straße 99, 37085, Göttingen, Germany

    W. Viöl

  4. Clausthaler Zentrum für Materialtechnik, Technische Universität Clausthal, Leibnizstrasse 4, 38678, Clausthal-Zellerfeld, Germany

    W. Maus-Friedrichs

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  1. S. Dahle
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  2. J. Meuthen
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  3. W. Viöl
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  4. W. Maus-Friedrichs
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Correspondence to W. Maus-Friedrichs.

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Dahle, S., Meuthen, J., Viöl, W. et al. Adsorption of silver on cellobiose and cellulose studied with MIES, UPS, XPS and AFM. Cellulose 20, 2469–2480 (2013). https://doi.org/10.1007/s10570-013-0009-1

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  • DOI: https://doi.org/10.1007/s10570-013-0009-1

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