Elsevier

Vacuum

Volume 41, Issues 1–3, 1990, Pages 352-355
Vacuum

Plenary Lecture
Exelfs of vanadium carbide with primary electrons of a few keV

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Grazing incidence electron energy loss spectroscopy with primary electrons of a few keV was applied to find the interatomic distance in the outer-most layer of a (111) single crystal surface of vanadium carbide V6C5. To compare with this, it was attempted to observe the energy loss spectrum of back-scattered electrons using a higher glancing angle for the same specimen. The atomic distance between vanadium and carbon was found to be 0.174 nm, which is considerably smaller than 0.207 nm, the bulk value. On the other hand, the spectrum of back-scattered electrons gave the distance 0.276 nm, which is much greater than the others. These results are discussed from the theoretical point of view.

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