Abstract
Raman scattering can detect spontaneous point-group symmetry breaking without resorting to single-domain samples. Here, we use this technique to study , the parent compound of the “122” Fe-based superconductors. We show that an applied compression along the Fe-Fe direction, which is commonly used to produce untwinned orthorhombic samples, changes the structural phase transition at temperature into a crossover that spans a considerable temperature range above . Even in crystals that are not subject to any applied force, a distribution of substantial residual stress remains, which may explain phenomena that are seemingly indicative of symmetry breaking above . Our results are consistent with an onset of spontaneous nematicity only below .
- Received 8 July 2015
DOI:https://doi.org/10.1103/PhysRevLett.115.197002
© 2015 American Physical Society