Microstructure and hardness development in a copper-nickel diffusion gradient model system

Cu has been electrolytically coated with Ni and subsequently deformed by rotary swaging up to a strain of e=2 to create a chemical gradient at the interface of the two elements. The extend of this chemical intermixing has been investigated through Energy Dispersive X- ray (EDX) spectroscopy in the Scanning and Transmission Electron Microscope (SEM and TEM). The depth, in which intermixing takes place, is about 1pm from the interface. Because of the uniform deformation, the structure does not get elongated but rather uniformly reduced in size. Microindentation hardness measurement shows a hardness increase from 120 to 135kp/mm² in the Cu phase with increasing strain. After annealing at 200°C for up to 4h the hardness first decreases, but raises above the value for the highly strained sample. The experimental findings are discussed with emphasis on surface mechanical alloying as a process of both scientific and technological interest.