Abstract
THE determination of stereochemistry without recourse to X-ray diffraction is usually more difficult for complexes of manganese(II) than for those of many other transition metal ions, for the two methods traditionally used—electronic spectroscopy and magnetic measurements—give little information in this case. The magnetic moment of the high spin d5 ion varies little from 5.92 B.M. Moreover, the d-d bands are spin-forbidden, so that they are very weak and difficult to observe, although it is sometimes possible to distinguish between 6 and 4-coordination.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Wickman, H. H., Klein, M. P., and Shirley, D. A., J. Chem. Phys., 42, 2113 (1965); Holluj, F., Canad. J. Phys., 44, 503 (1966); Griscom, D. L., and Griscom, R. E., J. Chem. Phys., 47, 2711 (1967).
Blumberg, W. E., Magnetic Resonance in Biological Systems (edit. by Ehrenberg, A., Malmström, B. E., and Vänngård, T.) (Pergamon, 1967).
Seed, T. J., J. Chem. Phys., 41, 1486 (1964).
Griffith, J. S., Mol. Phys., 8, 213 (1964).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
DOWSING, R., GIBSON, J., GOODGAME, D. et al. Determination of the Stereochemistry of Manganese(II) Complexes by Electron Spin Resonance. Nature 219, 1037–1038 (1968). https://doi.org/10.1038/2191037a0
Received:
Issue Date:
DOI: https://doi.org/10.1038/2191037a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
