Fundamental and overtone infrared spectra of CF3I

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Abstract

The i.r. spectra of CF3I between 250 and 5000 cm−1 have been measured with a resolution of 0.3–1 cm−1 and with optical path lengths up to 4 bar·10 m. A few bands of a sample cooled down to 180 K and several bands of a sample enriched in 13CF3I were also recorded. Values are assigned to most of the anharmonic xij and gii constants of 12CF3I. Serious perturbations occur however by Fermi resonance between ν1 and ν2 + ν3 and between ν1 and 2ν5, whose analysis is still very preliminary.

References (18)

  • L.C. Hoskins et al.

    J. Chem. Phys.

    (1973)
  • H. Bürger, K. Burczyk, R. Eujen and P. Schulz, private...
  • R.V. Ambartzumian et al.

    Acc. Chem. Res.

    (1977)
    R.V. Ambartzumian et al.C.D. Cantrell et al.C.D. Cantrell et al.

    Report of the Los Alamos Scientific Laboratory

    (1977)
    J.L. Lyman et al.J.L. Lyman et al.

    Report of the Los Alamos Scientific Laboratory

    (1979)
    P.A. Schulz et al.

    Ann. Rev. Phys. Chem.

    (1979)
    N. Bloembergen et al.

    Physics Today

    (1978)
    W. Fuss et al.

    Laboratory Report PLF

    (1980)
    W. Fuss et al.

    Progress in Quantum Electronics

    (1981)
  • W. Fuss et al.

    Ber. Bunsenges.

    (1979)
  • A.R.H. Cole
    (1977)
  • E.K. Plyler et al.

    J. Res.

    (1952)
  • P.R. McGee et al.

    J. Chem. Phys.

    (1953)
  • W.F. Edgell et al.

    J. Chem. Phys.

    (1954)
    W.F. Edgell et al.

    J. Chem. Phys.

    (1952)
  • R.J.H. Clark et al.

    Mol. Phys.

    (1975)
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