Disulfur complexes
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Cited by (275)
Synthesis of mixed salts of the [Mo<inf>2</inf>O<inf>2</inf>(μ-S)<inf>2</inf>(SCN)<inf>6-n</inf>(L)<inf>n</inf>]<sup>(4+n)</sup><sup>−</sup> anion (n = 0–2); structures of [Mo<inf>2</inf>O<inf>2</inf>(μ-S)<inf>2</inf>(SCN)<inf>5</inf>(CH<inf>3</inf>CN)]<sup>3−</sup>, [Mo<inf>2</inf>O<inf>2</inf>(μ-S)<inf>2</inf>(CN)<inf>5</inf>]<sup>3−</sup>, and [Mo<inf>2</inf>O<inf>2</inf>(μ-S)<inf>2</inf>(CN)<inf>2</inf>(O)]<sup>2−</sup>, and probing the ligand exchange of thiocyanate and cyanide
2021, PolyhedronCitation Excerpt :Binuclear molybdenyl complexes with the core structures [Mo2O2(μ-O)2]2+, [Mo2O2(μ-S)2]2+ and [Mo2S2(μ-S)2]2+, and the mixed O/S bridge [Mo2O2(μ-O)(μ-S)]2+ have been studied in many different contexts and their chemistry reviewed accordingly. [17–36] Numerous complexes with these core structures are known with terminal sulfur ligands where a common structure may be summarized as two molybdenum oxo or thio groups in the syn configuration with the Mo(V) centers in a square pyramidal geometry, or as one Mo(VI) in octahedral geometry and Mo(IV) in tetrahedral geometry [17–19,37]. Studies of enzymes and model compounds thereof with the [Mo2O2(μ-S)2]2+ core and terminal sulfur ligands such as disulfide or S22−, react with cyanide to form thiocyanate.[38–47] [
Effects of structural changes on the enhanced hydrogen evolution reaction for Pd NPs @ 2H-MoS<inf>2</inf> studied by in-Situ Raman spectroscopy
2021, Chemical Physics LettersCitation Excerpt :Moreover, Pd NPs decoration could offer the low activation potentials for H2 evolution and are often served as the active sites for H2 generation [11–13]. For Pd-MoS2 (Fig. 6), the bands at 234 cm−1 have a dramatic blue-shift, which may relate to the charge delocalization from the polarizable (soft) S22- ligand to the metal [26]. The bands at 335 cm−1 which attributed to coupled Mo-S are not be detected until the potential arrived at 0 mV (vs. RHE), the coupled Mo-S band (274 cm−1) would never appeared during the whole reaction, those results may related to the effects of Pd NPs decoration on the making and breaking chemical bonds of MoS2.
Insight into the superior activity of bridging sulfur-rich amorphous molybdenum sulfide for electrochemical hydrogen evolution reaction
2019, Applied Catalysis B: EnvironmentalCitation Excerpt :Firstly, S2- ligand of the MoS42- anion was oxidized by proton transfer from HCl and simultaneous generation of gaseous H2S. Subsequently, Mo6+ in MoS42− was reduced to Mo4+ by the process of electron transfer, leading to formation of Mo2S72− intermediate [30,35]. Thereafter, randomly bonded a-MoSx particles, composed of MoxSy clusters (where the average ratio of S/Mo is 3), were formed due to the continuous oxidation of S2− ligands in the MoS42− anions [32].
Structural change of molybdenum sulfide facilitates the electrocatalytic hydrogen evolution reaction at neutral pH as revealed by in situ Raman spectroscopy
2018, Cuihua Xuebao/Chinese Journal of Catalysis
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Present address: Hahn-Meitner-Institut, Glienicker Str. 100, 1000 Berlin 39, West Germany.
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Senior Alexander von Humboldt Awardee, 1981. Permanent address: Department of Chemistry, University of Arizona, Tucson, AZ 85721, U.S.A.