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Isolation and characterization of 3,5,6-trihydroxy-carotenoids from petals ofLilium tigrinum

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Summary

Reinvestigation by HPLC of the petals ofLilium tigrinum and the isolation of some minor compounds is reported. Using HPLC-controlled, preparative-column chromatography, 5,6-diakarpoxanthin (6), 6-epikarpoxanthin (2), 5,6-diacapsokarpoxanthin (8), and 9Z-antheraxanthin (9Z-13) were isolated and characterized. Based on spectroscopic data the absolute configurations of6 and8 were identical with those originating from paprika, thus the 5,6-diakarpoxanthin (6) and 5,6-diacapsokarpoxanthin (8) have the 3S, 5S, 6S configuration and 6-epikarpoxanthin (2) has the 3S, 5R, 6S configuration.

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Authors and Affiliations

  1. Department of Medical Chemistry, University Medical School of Pécs, P.O. Box 99, 7601, Pécs, Hungary

    J. Deli, P. Molnár, Z. Matus & G. Tóth

  2. Department of Chemistry and Biochemistry, University of Bern, Freiestr. 3, 3012, Bern, Switzerland

    A. Steck & H. Pfander

Authors
  1. J. Deli
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  2. P. Molnár
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  3. Z. Matus
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  4. G. Tóth
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  5. A. Steck
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  6. H. Pfander
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Deli, J., Molnár, P., Matus, Z. et al. Isolation and characterization of 3,5,6-trihydroxy-carotenoids from petals ofLilium tigrinum . Chromatographia 48, 27–31 (1998). https://doi.org/10.1007/BF02467511

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  • DOI: https://doi.org/10.1007/BF02467511

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