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Possibility of calculating the Rm values in thin-layer chromatography using a ternary mobile phase

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Summary

On the basis of an equation derived it is possible to establish theoretically the RM values for a ternary mobile phase. The RM values of phenol and its derivatives, naphthalene and its derivatives and some polycyclic aromatic hydrocarbons were measured. A good agreement has been found between the calculated and the experimentally obtained RM values. Analysis of the results showed some regularities of certain values obtained in binary systems when related to the ternary mobile phase.

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Ościk, J., Różyło, J.K., Gross, J. et al. Possibility of calculating the Rm values in thin-layer chromatography using a ternary mobile phase. Chromatographia 15, 25–29 (1982). https://doi.org/10.1007/BF02269035

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