Rodlike micelles of dimethyloleylamine oxide in aqueous NaCl solutions, and their flexibility and size distribution

Abstract

Angular dependence of light scattering from aqueous NaCl solutions of dimethyloleylamine oxide has been measured in the presence of NaCl from 5×10⁻⁴ M to 10⁻¹ M at 25 °C. The molecular weight and radius of gyration of micelles increase with increasing micelle concentration and reach constant values, suggesting occurrence of the sphere-rod equilibrium dependent on the micelle concentration. With increasing NaCl concentration, rodlike micelles are larger in molecular weight and become longer. The micelles formed at NaCl concentrations higher than 10⁻³ M are nearly monodisperse when the micelle concentration is high.

Rodlike micelles of dimethyloleylamine oxide in 10⁻² M and 5 × 10⁻² M NaCl solutions have molecular weights of 4,760,000 and 6,900,000, respectively, and behave as semi-flexible or wormlike chains. In 5×10⁻² M NaCl they have a contour length of 5750 Å and a persistence length of 1760 Å. These micelle parameters correspond to the end-to-end distance of 3780 Å and the number of Kuhn's statistical segments of 1.64. The large aggregation number of the rodlike micelles is induced by the strong cohesion of long hydrocarbon chains in solution, and their flexibility is caused by the hydration of amine oxide groups.