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Chirale Erkennung bei Trisdiimin-Metallkomplexen: 3. Adsorption von Tris-(3,3′-bi-1,2,4-triazin)eisen(II)-Komplexen an Montmorillonit

Chiral recognition among trsidiimine-metal complexes: 3. Adsorption of tris-(3,3′-bi-1,2,4-triazine)iron(II) complexes onto montmorillonite

  • Anorganische Und Physikalische Chemie
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Summary

Adsorptionisotherms of tris-(3,3′-bi-1,2,4-triazine)iron(II) complexes onto a well characterized montmorillonite are discussed in respect to the relative charge densities of adsorbent and adsorbat. While the adsorption capacities for trisbipyridyl and trisphenanthroline complexes differ for the racemates and the enantiomers they are equal for these complexes. Adsorption is limited to a monolayer. This backs the proposal that the observed chiral recognition phenomena are founded solely in the lateral interactions between adsorbats.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Universität Regensburg, D-93053, Regensburg, Bundesrepublik Deutschland

    J. Breu & K. -J. Range

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  1. J. Breu
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  2. K. -J. Range
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Breu, J., Range, K.J. Chirale Erkennung bei Trisdiimin-Metallkomplexen: 3. Adsorption von Tris-(3,3′-bi-1,2,4-triazin)eisen(II)-Komplexen an Montmorillonit. Monatsh Chem 125, 153–165 (1994). https://doi.org/10.1007/BF00818162

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  • DOI: https://doi.org/10.1007/BF00818162

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