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Kristallstruktur von N,N,N′,N′-Tetraisopropyl-p-phenylen-diammonium-dichlorid und-bis(tetrachloroaluminat)

Crystal structure of N,N,N′,N′-tetraisopropyl-p-phenylene-diammonium dichloride and-bis(tetrachloroaluminate) (short comm.)

Kurze Mitteilung

  • Anorganische Und Physikalische Chemie
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Summary

Protonation of the sterically overcrowded N,N,N′,N′-tetraisopropyl-p-phenylenediamine leads to a significant shortening of the C-N bond lengths of 7 pm as well as to a widening of the phenyl ipso-angle to 122°. All structural changes can be attributed to the twisted diisopropylammonium substituents and their electron acceptor properties.

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Authors and Affiliations

  1. Chemische Institute der J.-W.-Goethe-Universität, D-60439, Frankfurt/Main, Germany

    C. Näther, I. Göbel & H. Bock

  2. Institut für Anorganische Chemie der Technischen Universität, D-85748, München, Germany

    E. Herdtweck

Authors
  1. C. Näther
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  2. I. Göbel
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  3. H. Bock
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  4. E. Herdtweck
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Näther, C., Göbel, I., Bock, H. et al. Kristallstruktur von N,N,N′,N′-Tetraisopropyl-p-phenylen-diammonium-dichlorid und-bis(tetrachloroaluminat). Monatsh Chem 128, 841–848 (1997). https://doi.org/10.1007/BF00807094

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  • DOI: https://doi.org/10.1007/BF00807094

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