Abstract
The reaction rate constant and the order of the reaction of 2-dimethylamino-[1,3,2]dioxarsolane with diphenylamine are determined. The order of the reaction proves the mechanism, which is discussed for the cleavage of the As−N bond by acid molecules.
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F. Kober, Chemiker-Ztg.100, 313 (1976), dort weitere Zitate.
J. Singh undA. B. Burg, J. Amer. Chem. Soc.88, 718 (1966);K. Sommer, W. Lauer undM. Becke-Goehring, Z. anorg. allg. Chem.379, 48 (1970);L. S. Sagan, R. A. Zingaro undK. J. Irgolic, J. Organomet. Chem.39, 301 (1972);F. Kober, J. Fluorine Chem.2, 247 (1972/73); Z. anorg. allg. Chem.401, 243 (1973);400, 285 (1973);397, 97 (1973);H. J. Vetter, H. Nöth undU. Hayduk, Z. anorg. allg. Chem.331, 35 (1964);I. G. Morse undW. Küren, Inorg. Chem.12, 2119 (1973);J. Kaufmann undF. Kober, J. Organometal. Chem.82, 333 (1974);81, 59 (1974);71, 49 (1974);O. Adler undF. Kober, J. Fluorine Chem.5, 231 (1975); Z. Naturforsch.31 b, 304 (1976); J. Organometal. Chem.72 351 (1974);H. J. Vetter undH. Nöth, Z. anorg. allg. Chem.330, 233 (1964);R. J. Singer, M. Eisenhut undR. Schmutzler, J. Fluorine Chem.1, 193 (1971/72);F. Kober undW. J. Rühl, Z. anorg. allg. Chem.403, 56 (1974);406, 52 (1974).
F. Kober, Z. Chem.16, 159 (1976);J. Kaufmann, F. Kober undL. Zimmer, l. c.16, 279 (1976);F. Kober, W. J. Rühl undL. Zimmer, l. c.16, 232 (1976).
O. Adler undF. Kober, Chem.-Ztg.100, 235 (1976); J. Prakt. Chem., im Druck.
K. Sommer undM. Becke-Goehring, Z. anorg. allg. Chem.355 192 (1967).
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Adler, O., Kober, F. Kinetische Messung der Umaminierung des 2-Dimethylamino-[1.3.2.]dioxarsolans mit Diphenylamin. Monatshefte für Chemie 108, 647–651 (1977). https://doi.org/10.1007/BF00912810
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DOI: https://doi.org/10.1007/BF00912810