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Zur Kenntnis der Reaktionsfähigkeit alkylsubstituierter Thiomorpholine, 1. Mitt.

Concomitant action of elementary sulfur and gaseous ammonia upon ketones, LXXIX: On the reactivity of alkyl substituted thiomorpholines, I

Über die gemeinsame Einwirkung von elementarem Schwefel und gasförmigem Ammoniak auf Ketone, 79. Mitt.

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Abstract

The preparation of someMannichbases (3 a-f) andMannich base hydrochlorides (2 a-f), resp., and numerous s-triazine derivatives (4 a-d, 5 a–m, 6 a–w, 7 a–e, 8 a–d, and9 a–l) based upon unsubstituted thiomorpholine (1 a) as well as C-mono-[2-methylthiomorpholine (1 b) and 2-ethylthio-morpholine (1 c)] and C-dialkylated thiomorpholines [2-methyl-3-ethylthiomorpholine (1 d)] is described.

Zusammenfassung

Die Darstellung einigerMannichbasen (3 a-f) bzw.Mannich-basen-hydrochloride (2 a-f) und zahlreicher s-Triazin-Derivate (4 a-d, 5 a–m, 6 a–w, 7 a–e, 8 a–d, und9 a–l) auf Basis des unsubstituierten Thiomorpholins (1 a) sowie C-mono-[2-Methylthiomorpholin (1 b) und 2-Äthylthiomorpholin (1 c)] und C-dialkylierter Thiomorpholine [2-Methyl-3-äthylthiomorpholin (1 d)] wird beschrieben.

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Author notes

  1. H. Offermanns

    Present address: Zweigniederlassung der Degussa, Chemiewerk Homburg, Daimlerstraße 25, D-6, Frankfurt/Main

  2. D. Neuray

    Present address: Farbenfabriken Bayer AG., Werk Uerdingen, Rheinufer-Str. 7-9, D-415, Krefeld-Uerdingen

Authors and Affiliations

  1. Institut für Technische Chemie und Petrolchemie der Rheinisch-Westfälischen Technischen Hochschule Aachen, Bundesrepublik Deutschland

    F. Asinger, H. Offermanns, A. Saus, C. Dudeck, D. Neuray & E. Wilms

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  1. F. Asinger
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  2. H. Offermanns
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  3. A. Saus
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  4. C. Dudeck
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  5. D. Neuray
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  6. E. Wilms
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Additional information

HerrE. Wilms dankt der Deutschen Texaco AG. für die Gewährung eines Stipendiums herzlichst.

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Asinger, F., Offermanns, H., Saus, A. et al. Zur Kenntnis der Reaktionsfähigkeit alkylsubstituierter Thiomorpholine, 1. Mitt.. Monatshefte für Chemie 104, 118–136 (1973). https://doi.org/10.1007/BF00911153

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  • DOI: https://doi.org/10.1007/BF00911153

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