Skip to main content
Log in

Application of real-time mass spectrometric techniques to environmental organic geochemistry II. Organic matter in San Francisco bay area water

  • Published:
Archives of Environmental Contamination and Toxicology Aims and scope Submit manuscript

Abstract

A preliminary study was made of the solvent-soluble (organic) matter passing through a fine fritted filter in samples of water taken from the San Francisco and San Pablo bays, the Carquinez Strait, and an estuary in the confluence of the Sacramento and San Joaquin rivers. The petroleum ether extracts (ranging from 2.5 to 102 µg/liter) were analyzed using gas chromatography, computer-coupled gas chromatography/mass spectrometry, and high-resolution mass spectrometry. The organic compounds identified in these extracts are quite diverse and consist mainly of hydrocarbons from various sources. Some phthalate esters occur at various sampling sites. The conclusion is that the techniques of gas chromatography/mass spectrometry and high-resolution mass spectrometry are ideally suited to the assessment of some of the potential interactions of pollutants and other organic compounds in the aquatic environment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Boylan, D. B.: Private communication (1971).

  • Boylan, D. B., and B. W. Tripp: Determination of hydrocarbons in sea water extracts of crude oil and crude oil fractions. Nature230 44 (1971).

    PubMed  Google Scholar 

  • Burlingame, A. L.: Data acquisition, processing and interpretation via coupled highspeed real-time digital computer and high-resolution mass spectrometer systems. In Kendrick, E. (ed.): Advances in mass spectrometry, vol. 4, p. 15. London: The Institute of Petroleum (1968).

    Google Scholar 

  • Burlingame, A. L., and D. H. Smith: Automated heteroatomic plotting as an aid to the presentation and interpretation of high-resolution mass spectral data. Tetrahedron24 5749 (1968).

    Google Scholar 

  • Burlingame, A. L.: Developments and applications of real-time high-resolution mass spectrometry. In Ogata, K. and T. Hayakawa (eds.): Recent developments in mass spectrometry, p. 104. Tokyo: University of Tokyo Press (1970).

    Google Scholar 

  • Burlingame, A. L., D. H. Smith, T. O. Merren, and R. W. Olsen: Real-time high-resolution mass spectrometry. In Orr, C. H. and J. Norris (eds.): Computers in analytical chemistry, vol. 4 of Progress in Analytical Chemistry Series, p. 17. New York: Plenum Press (1970).

    Google Scholar 

  • Chang, J. J., F. C. Walls, D. H. Smith, B. R. Simoneit, and A. L. Burlingame: The LOGOS classifier—a compound classifier based on computer analysis of mass spectrometric data. In preparation (1973).

  • Ciaccio, L. L., (ed.): Water and water pollution handbook. See especially Painter, H. A.: Chemical, physical and biological characteristics of wastes and waste effluents, vol. 1, chapter 7. New York: M. Dekker (1971).

    Google Scholar 

  • Eglinton, G., and M. T. J. Murphy (eds.): Organic geochemistry methods and results. Heidelberg: Springer-Verlag (1969).

    Google Scholar 

  • Garrison, A. W., L. H. Keith, and M. M. Walker: The use of mass spectrometry in the identification of organic contaminants in water from the Kraft paper mill industry. In: Proc. 18th annual conference on mass spectrometry and allied topics, p. B205. San Francisco, California, June 1970.

  • Hites, R. A., and K. Biemann: Computer evaluation of continuously scanned mass spectra of gas chromatographic effluents. Anal. Chem.42 855 (1970).

    Google Scholar 

  • Hood, D. W. (ed.): Symposium on organic matter in natural waters.University of Alaska: Institute of Marine Science (1970).

  • Jaeger, R. J., and R. J. Rubin: Plasticizers from plastic devices: Extraction, metabolism, and accumulation by biological systems. Science170 460 (1970).

    PubMed  Google Scholar 

  • Lee, R. F., J. C. Nevenzel, and G. A. Paffenhöfer: Importance of wax esters and other lipids in the marine food chain: phytoplankton and copepods. Marine Biology9 99 (1971).

    Google Scholar 

  • Scher, J. A.: Measurement of trace organic pollutants in aqueous solutions. Amer. Lab.2 24 (1970).

    Google Scholar 

  • Schmidt, T. T., R. W. Risebrough, and F. Gress: Input of polychlorinated biphenyls into California coastal waters from urban sewage outfalls. Bull. Environ. Contam. Toxicol.6 235 (1971).

    PubMed  Google Scholar 

  • Simoneit, B. R., and D. A. Flory: Apollo 11, 12 and 13 Organic Contamination Monitoring History. NASA Division Internal Note, MSC 04350,NASA-Manned Spacecraft Center, Houston (May 1971).

  • Simoneit, B. R.: Apollo 14 organic contamination monitoring history. University of California Space Sciences Laboratory Report, in press (1973a).

  • Simoneit, B. R.: Organic analyses of Black Sea cores. In Degens, E.T. and D.A. Ross (eds.): The Black Sea: geology, chemistry and biology, in the Memoir Series of the American Association of Petroleum Geologists, in press 1973b).

  • Simoneit, B. R., and A. L. Burlingame: Preliminary organic analyses of the DSDP (JOIDES) cores, legs V-IX. In von Gaertner, H. and H. Wehner (eds.): Advances in organic geochemistry 1971, p. 189. Oxford-Braunschweig: Pergamon Press (1972).

    Google Scholar 

  • Simoneit, B. R., D. H. Smith, G. Eglinton, and A. L. Burlingame: Applications of real-time mass spectrometric techniques to environmental organic geochemistry. I. General considerations. In preparation (1973).

  • Smith, D. H., R. W. Olsen, F. C. Walls, and A. L. Burlingame: Real-time mass spectrometry: LOGOS—a generalized mass spectrometry computer system for high and low resolution, gas chromatography/mass spectrometry, and closed-loop applications. Anal. Chem.43 1796 (1971).

    Google Scholar 

  • Smith, D. H.: A compound classifier based on computer analysis of low-resolution mass spectral data. Geochemical and environmental applications. Anal. Chem.44 536 (1972).

    Google Scholar 

  • Taras, M. J., A. E. Greenberg, R. D. Hoak, and M. C. Rand (eds.): Standard methods for the examination of water and waste-water, 13 ed., pp. 254–256. New York: American Public Health Assoc. (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

For part I., see Simoneitet al. (1973).

John Simon Guggenheim Memorial Fellow, 1970–72.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Simoneit, B.R., Smith, D.H., Eglinton, G. et al. Application of real-time mass spectrometric techniques to environmental organic geochemistry II. Organic matter in San Francisco bay area water. Arch. Environ. Contam. Toxicol. 1, 193–208 (1973). https://doi.org/10.1007/BF01985744

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01985744

Keywords

Navigation