Thermodynamics of feldspathoid solutions

Abstract

We have developed models for the thermody-namic properties of nephelines, kalsilites, and leucites in the simple system NaAlSiO₄−KAlSiO₄−Ca_0.5AlSiO₄−SiO₂−H₂O that are consistent with all known constraints on subsolidus equilibria and thermodynamic properties, and have integrated them into the existing MELTS software package. The model for nepheline is formulated for the simplifying assumptions that (1) a molecular mixing-type approximation describes changes in the configurational entropy associated with the coupled exchange substitutions □Si?NaAl and □Ca? Na₂ and that (2) Na⁺ and K⁺ display long–range non-convergent ordering between a large cation and the three small cation sites in the Na₄Al₄Si₄O₁₆ formula unit. Notable features of the model include the prediction that the mineral tetrakalsilite (“panunzite”, sensu stricto) results from anti-ordering of Na and K between the large cation and the three small cation sites in the nepheline structure at high temperatures, an average dT/dP slope of about 55^°/kbar for the reaction

over the temperature and pressure ranges 800–1050 ^°C and 500–5000 bars, roughly symmetric (i.e. quadratic) solution behavior of the K–Na substitution along joins between fully ordered components in nepheline, and large positive Gibbs energies for the nepheline reciprocal reactions

and

and for the leucite reciprocal reaction