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Phase relations between Ca3Fe 32 +Si3O12-Fe 23 +Fe 32 +Si3O12 garnet and CaFeSi2O6-Fe2Si2O6 pyroxene solid solutions

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References

  • Amthauer G, Annersten H, Hafner SS (1976) The Mössbauer spectrum of 57Fe in silicate garnets. Zeit Kristallogr 143: 14–55

    Google Scholar 

  • Angel RJ, Chopelas A, Ross NL (1992) Stability of high-density clinoenstatite at upper mantle pressures. Nature 358: 322–324

    Article  Google Scholar 

  • Anovitz LM, Essene EJ (1987) Compatibility of geobarometers in the system CaO-FeO-Al2O3-SiO2-TiO2 (CFAST):implications for garnet mixing models. J Geol 95: 633–645

    Article  Google Scholar 

  • Cameron M, Sueno S, Prewitt CW, Papike JJ (1973) High-temperature crystal chemistry of acmite, diopside, hedenbergite, jadite, spodumene, and ureyite. Am Mineral 58: 594–618.

    Google Scholar 

  • Chou I-M (1986) Permeability of precious metals to hydrogen at 2 kbar total pressure and elevated temperatures. Am J Sci286: 638–658

    Google Scholar 

  • Davidson PM, Lindsley DH (1985) Thermodynamic analysis of quadrilateral pyroxenes. II. Model calibration from experiments and application to geothermometry. Contrib Mineral Petrol 91: 390–404

    Article  Google Scholar 

  • Davidson PM, Grover J, Lindsley DH (1982) (Ca,Mg)2Si2O6 clinopyroxenes:a solution model based on nonconvergent site-disorder. Contrib Mineral Petrol 80: 88–102

    Article  Google Scholar 

  • Ganguly J, Saxena SK (1984) Mixing properties of aluminosilicate garnet:constraints from natural and experimental data, and application to geothermo-barometry. Am Mineral 69: 88–97

    Google Scholar 

  • Gasparik T (1990) A thermodynamic model for the enstatite-diop-side join. Am Mineral 75: 1080–1091

    Google Scholar 

  • Geiger CA, Newton RC, Kleppa OJ (1987) Enthalpy of mixing of synthetic almandine-grossular and almandine-pyrope garnets from high temperature solution calorimetry. Geochim Cos-mochim Acta 51: 1755–1763.

    Article  Google Scholar 

  • Geiger CA, Merwin L, Sebald A (1990) Ordering studies in grossular and pyrope garnets using 29Si NMR and 57Fe Mössbauer spec-troscopy. Terra Abstr 2: 75

    Google Scholar 

  • Gudmundsson G, Wood BJ (1995) Experimental tests of garnet peridotite oxygen barometry. Contrib Mineral Petrol 119: 56–67

    Article  Google Scholar 

  • Gustafson WI (1974) The stability of andradite, hedenbergite, and related minerals in the system Ca-Fe-Si-O-H. J. Petrol 15: 455–496

    Google Scholar 

  • Holland TJB, Powell R (1990) An enlarged and updated internally consistent dataset with uncertainties and correlations:the system K2O-Na2O-CaO-MgO-FeO-Fe2O3-Al2O3-TiO2-SiO2-C-H2-O2. J Metamorphic Petrol 8: 89–124

    Article  Google Scholar 

  • Huckenholz HG, Yoder HS (1971) Andradite stability relations in the CaSiO3-Fe2O3 join. Neues Jahrb Mineral Abh 114: 246–280

    Google Scholar 

  • Huckenholz HG, Schairer JF, Yoder HSJr (1969) Synthesis and stability of ferri-diopside. Mineral Soc Am Spec Pap 2: 163–177

    Google Scholar 

  • Hugh-Jones DA, Woodland AB, Angel RJ (1994) The structure of high-pressure C2/c ferrosilite and crystal chemistry of high-pressure C2/c pyroxenes. Am Mineral 79: 1032–1041

    Google Scholar 

  • Johnson RE, Muan A (1967) Activity-composition relations in solid solutions of the system CaO—“FeO”—SiO2 in contact with metallic iron at 1080°C. Trans Metal Soc AIME 239: 1931–1939

    Google Scholar 

  • Köhler TP, Brey GP (1990) Calcium exchange between olivine and clinopyroxene calibrated as a geothermometer for natural peridotites from 2 to 60 kbar with applications. Geochim Cos-mochim Acta 54: 2375–2388

    Article  Google Scholar 

  • Koziol AM (1990) Activity-composition relationships of binary Ca-Fe and Ca-Mn garnets determined by reversed, displaced equilibrium experiments. Am Mineral 75: 319–327

    Google Scholar 

  • Lindsley DH (1967) The join hedenbergite-ferrosilite at high pressures and temperatures. Carnegie Inst Washington Yearbook 64: 230–232

    Google Scholar 

  • Lindsley DH (1980) Phase equilibria of pyroxenes at pressures > 1 atmosphere. In:Prewitt CW (ed) Pyroxenes:(Reviews in Mineralogy, vol 7): Mineral Soc Am, Washington, DC, 289–308

    Google Scholar 

  • Lindsley DH (1981)The formation of pigeonite on the join hedenbergite-ferrosilite at 11.5 and 15 kbar: experiments and a solution model. Am Mineral 66: 1175–1182

    Google Scholar 

  • Lindsley DH, Munoz JL (1969) Subsolidus relations along the join hedenbergite-ferrosilite. Am J Sci 267-A: 295–324

    Google Scholar 

  • Liou JG (1974) Stability relations of andradite-quartz in the system Ca-Fe-Si-O-H. Am Mineral 59: 1016–1025

    Google Scholar 

  • Lucas H, Muggeridge MT, McConchie DM (1989) Iron in kimberlitic ilmenites and chromian spinels:a survey of analytical techniques. In:Ross J (ed) Kimberlites and related rocks, vol 2, Geol Soc of Aust Spec Publ, Blackwell, Australia, pp 311–319

    Google Scholar 

  • Luth RW, Virgo D, Boyd FR, Wood BJ (1990) Ferric iron in mantle-derived garnets, implications for thermobarometry and for the oxidation state of the mantle. Contrib Mineral Petrol 104: 56–72.

    Article  Google Scholar 

  • Massalski TB, Murray JL, Bennett LH, Baker H (1986) Binary alloy phase diagrams, Am Soc Met, Metals Park, Ohio, USA, pp 24–26.

    Google Scholar 

  • Moecher DP, Essene EJ, Anovitz LM (1988) Calculation and application of clinopyroxene-garnet-plagioclase-quartz geo-barometers. Contrib Mineral Petrol 100: 92–106

    Article  Google Scholar 

  • Ohashi Y, Burnham CW, Finger LW (1975) The effect of Ca-Fe substitution on the clinopyroxene crystal structure. Am Mineral 60: 423–434

    Google Scholar 

  • Robie RA, Bin Y, Hemingway BS, Barton MD (1987) Heat capacity and thermodynamic properties of andradite garnet Ca3Fe2Si3O12, between 10 and 1000 K and revised values for ΔfG om (298.15 K) of hedenbergite and wollastonite. Geochim Cosmochim Acta 51: 2219–2224

    Article  Google Scholar 

  • Ross II CR, Armbruster T, Canil D (1992) Crystal structure refinement of a spinelloid in the system Fe3O4.-Fe2SiO4. Am Mineral 77: 507–511

    Google Scholar 

  • Roth RS, Dennis JR, McMurdie HF (1987) Phase diagrams for ceramisists, vol VI.Am Ceram Soc, Westerville, Ohio, USA, pp 454–456

    Google Scholar 

  • Schwartz KB, Nolet DA, Burns RG (1980) Mössbauer spectroscopy and crystal chemistry of natural Fe-Ti garnets. Am Mineral 65: 142–153

    Google Scholar 

  • Sueno S, Kimata M, Prewitt CW (1984) The crystal structure of high clinoferrosilite. Am Mineral 69: 264–269

    Google Scholar 

  • Suwa Y, Tamai Y, Naka S (1976) Stability of synthetic andradite at atmospheric pressure. Amer Mineral 61: 26–28

    Google Scholar 

  • Taylor BE, Liou JG (1978) The low temperature stability of andradite in C-O-H fluids.Am Mineral 63: 378–393

    Google Scholar 

  • Wood BJ, Nicholls J (1978) The thermodynamic properties of reciprocal solid solutions. Contrib Mineral Petrol 66: 389–400

    Article  Google Scholar 

  • Woodland AB, O’Neill HStC (1993) Synthesis and stability of Fe 23 + Fe 32 + Si3O12 garnet and phase relations with Fe3Al2Si3O12-Fe 23 + Fe 32 + Si3O12 solutions. Am Mineral 78: 1000–1013

    Google Scholar 

  • Woodland AB, RossII CR (1994) A crystallographic and Mössbauer spectroscopy study of Fe3Al2Si3O12-Fe 23 + Fe 32 + Si3O12 (almandine-skiagite) and Ca3Fe 32 + Si3O12-Fe 23 + Fe 32 + Si3O12 (andradite-skiagite) garnet solid solutions. Phys Chem Miner 21: 117–132

    Article  Google Scholar 

  • Zhang Z, Saxena SK (1991) Thermodynamic properties of andradite and application to skarn with coexisting andradite and hedenbergite. Contrib Mineral Petrol 107: 255–263

    Article  Google Scholar 

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  1. Bayerisches Geoinstitut, Universität Bayreuth, D-95440, Bayreuth, Germany

    Alan B. Woodland & Hugh St. C. O’Neill

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  1. Alan B. Woodland
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  2. Hugh St. C. O’Neill
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Editorial responsibility: J. Hoefs

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Woodland, A.B., O’Neill, H.S.C. Phase relations between Ca3Fe 32 +Si3O12-Fe 23 +Fe 32 +Si3O12 garnet and CaFeSi2O6-Fe2Si2O6 pyroxene solid solutions. Contrib Mineral Petrol 121, 87–98 (1995). https://doi.org/10.1007/s004100050091

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