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Soret effect in forced Rayleigh scattering

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Abstract

In forced Rayleigh scattering of mixtures or suspensions the temperature gratings generate, by the Soret effect, concentration gratings that may be very important since they produce both a phase and an amplitude grating superimposed on the principal one. The experimental evidence of their influence was given by Thyagarajan and Lallemand using a mixture of carbondisulfide and ethanol. In this paper we study the temporal behaviour of the concentration grating versus the sample properties and its effect on the detected diffracted beam. Explicit expressions are given for the output intensity taking into account both the generated amplitude and phase gratings.

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Bloisi, F., Vicari, L., Cavaliere, P. et al. Soret effect in forced Rayleigh scattering. Appl. Phys. B 44, 103–106 (1987). https://doi.org/10.1007/BF00694201

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  • DOI: https://doi.org/10.1007/BF00694201

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