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Azoxyarylene compounds and polymers by a copper-pyridine catalyzed oxidative coupling reaction

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Summary

Azoxyarylene compounds can be quantitatively formed by oxidative coupling of N-arylhydroxylamines in the presence of a copper-pyridine catalyst and dioxygen. This new method was utilized to synthesize a poly(azoxy arylene). Polymer 5 obtained has a weight average molecular weight of 6,500 and a number average molecular weight of 4,400.

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Authors and Affiliations

  1. C. S. Marvel Laboratories, Department of Chemistry, The University of Arizona, Tucson, AZ 85721, USA, , , , , , US

    Yong Ding, Anne Buyle Padias & H. K. Hall Jr.

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  1. Yong Ding
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  2. Anne Buyle Padias
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  3. H. K. Hall Jr.
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Received: 1 February 1999/Revised version: 23 April 1999/Accepted: 23 April 1999

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Ding, Y., Buyle Padias, A. & Hall Jr., H. Azoxyarylene compounds and polymers by a copper-pyridine catalyzed oxidative coupling reaction. Polymer Bulletin 42, 689–692 (1999). https://doi.org/10.1007/s002890050520

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  • DOI: https://doi.org/10.1007/s002890050520

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