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Synthesis and characterization of the novel cellulose derivative dansyl cellulose

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Summary

Novel, soluble 5-dimethylamino-1-naphthalenesulfonyl esters of cellulose (2) with a degree of substitution from 0.67 to 1.59 were prepared by esterification of cellulose dissolved in N,N-dimethylacetamide/LiCl solvent system and characterized by means of FTIR-as well as 1H and 13C NMR-spectroscopy. The remaining OH groups of 2 can be fully acetylated in pyridine using N,N-dimethylaminopyridine as a catalyst. The polymers show typical fluorescence and absorption spectra with absorptions at 217, 250 and 317 nm which are in good agreement with quantum chemical calculations.

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Authors and Affiliations

  1. Institute of Organic Chemistry and Macromolecular Chemistry, Friedrich Schiller University of Jena, Humboldtstrasse 10, D-07743, Jena, Germany

    T. Heinze & J. A. Camacho Gómez

  2. Institute of Physical Chemistry, Friedrich Schiller University of Jena, Lessingstrasse 10, D-07743, Jena, Germany

    G. Haucke

Authors
  1. T. Heinze
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  2. J. A. Camacho Gómez
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  3. G. Haucke
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Heinze, T., Camacho Gómez, J.A. & Haucke, G. Synthesis and characterization of the novel cellulose derivative dansyl cellulose. Polymer Bulletin 37, 743–749 (1996). https://doi.org/10.1007/BF00295772

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  • DOI: https://doi.org/10.1007/BF00295772

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