Summary
The equilibrium water contents of linear poly(acrylic acid) sodium salts with different degrees of neutralisation were found to be dependent on temperature and relative humidity. An octahedral model for the primary hydration of poly(acrylic acid) sodium salts (HIRAOKA and YOKOYAMA 1980) was critically evaluated in the light of these findings and an anomaly in the water uptake versus neutralisation curve at approximately 33% neutralisation was explained by the counterion condensation theory. (MANNING 1979).
Similar content being viewed by others
References
HIRAOKA, K.; SHIN, H. and YOKOYAMA, T: Polym. Bull. (Berlin) 8, 303–309 (1982)
HIRAOKA, K. and YOKOYAMA, T.: Polym. Bull. (Berlin) 2, 183–188 (1980)
KODA, S.; NOMURA, H, and NAGASAWA, M.: Biophys. Chem. 15, 65–72 (1982)
MANNING, G.: Acc. Chem. Res. 12, 443–449 (1979)
NEWMAN, S.; KRIGBAUM, W.; LAUGIER, C. and FLORY, P.: J. Polym. Sci 14, 451–462(1954)
NODA, I.; TSUGE, T. and NAGASAWA, M.: J. Phys. Chem. 74, 710–719 (1970)
WHISTLER, R.: Tappi 60, 65 - 70 (1970)
YOUNG, J.: J. Appl. Chem. 17, 241–245 (1967)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Buchanan, K.J., Hird, B. & Letcher, T.M. Primary hydration of poly(acrylic acid) sodium salts. Polymer Bulletin 13, 493–498 (1985). https://doi.org/10.1007/BF00263469
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00263469