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Absolute configurational assignments for the1H-NMR spectrum of poly(vinyl alcohol) by use of two-dimensional NMR methods

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Summary

FOCSY two-dimensional J-resolved NMR spectroscopy is used to resolve1H NMR resonances corresponding to triad and tetrad configurations of poly(vinyl alcohol). Two-dimensional auto correlation with ω1-scaling NMR spectroscopy is used to observe connectivities between triad and tetrad1H NMR resonances. Comparison of these connectivities to the necessary compositional relationships at triad-tetrad level leads to absolute configurational assignments for the1H NMR spectrum of poly(vinyl alcohol).

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References

  1. S. Macura and L.R. Brown, J. Magn. Reson. 53, 529 (1983).

    Google Scholar 

  2. L.R. Brown, J. Magn. Reson. 57, 513 (1984).

    Google Scholar 

  3. A. Bax, S.P. Kempsall and R. Freeman, J. Magn. Reson. 41, 349 (1980).

    Google Scholar 

  4. K. Nagayama, A. Kumar, K. Wüthrich and R.R. Ernst, J. Magn. Reson. 40, 321 (1980).

    Google Scholar 

  5. F.A. Bovey, “High Resolution NMR of Macromolecules,” Academic Press, New York, (1972).

    Google Scholar 

  6. W.P. Aue, J. Karhan and R.R. Ernst, J. Chem. Phys. 64, 4226 (1976).

    Google Scholar 

  7. K. Nagayama, P. Bachmann, K. Wüthrich and R.R. Ernst, J. Magn. Reson. 31, 133 (1978).

    Google Scholar 

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Authors and Affiliations

  1. Michigan Molecular Institute, 48640, Midland, Michigan, USA

    G. P. Gippert & L. R. Brown

Authors
  1. G. P. Gippert
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  2. L. R. Brown
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Gippert, G.P., Brown, L.R. Absolute configurational assignments for the1H-NMR spectrum of poly(vinyl alcohol) by use of two-dimensional NMR methods. Polymer Bulletin 11, 585–592 (1984). https://doi.org/10.1007/BF01045342

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  • DOI: https://doi.org/10.1007/BF01045342

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