Abstract
Hard mode Raman Spectroscopy and optical birefringence studies have been used to evaluate the temperature behaviour of order parameters for the cubictetragonal phase transition in leucite. There is a strong temperature-dependence of Raman line frequencies near 498 cm−1 and 529 cm−1, and the optical birefringence decreases towards zero on heating. Above the transition temperature leucite still shows slight birefringence, which correlates with the persistence of the 200 X-ray reflexion at these temperatures, and is not compatible with the ideal cubic symmetry. Quantitative observations of the temperature evolution of Raman line-frequencies and the birefringence are consistent with an order parameter showing T 1g symmetry, and a nearly-tricritical phase transition behaviour. The results of earlier X-ray and DSC studies imply the operation of an additional order parameter, with E g symmetry; this is observed, but its influence on the transition behaviour is significant only at temperatures close to T c. The two order parameters are related via linear-quadratic or biquadratic coupling. We develop the form of the Landau Potential for leucite — including both order parameters and their couplings — to discuss the present observations and previous structural data.
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Palmer, D.C., Bismayer, U. & Salje, E.K.H. Phase transitions in leucite: Order parameter behaviour and the Landau potential deduced from Raman spectroscopy and birefringence studies. Phys Chem Minerals 17, 259–265 (1990). https://doi.org/10.1007/BF00201458
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DOI: https://doi.org/10.1007/BF00201458