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Retention indices of 28 polychlorinated biphenyls in capillary gas chromatography referred to 2,4,6-trichlorophenyl alkyl ethers as RI-standards

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Abstract

An homologous series of eight 2,4,6-trichlorophenyl alkyl ethers (TCPE) was synthesized. The TCPE has been conceived to be used as retention index markers in the gas chromatography with the atomic emission detector (AED), the electron capture detector (ECD) and the mass spectrometric detector (MSD). On the basis of the TCPE, the retention indices of 28 polychlorinated biphenyls have been determined using the ECD, a 95% dimethyl 5% phenyl polysiloxane phase and six different temperature programs.

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Authors and Affiliations

  1. Abteilung Analytische Chemie und Umweltchemie, Universität Ulm, Albert-Einstein-Allee 11, D-89069, Ulm-Donau, Germany

    Marco Morosini & Karlheinz Ballschmiter

Authors
  1. Marco Morosini
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  2. Karlheinz Ballschmiter
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Morosini, M., Ballschmiter, K. Retention indices of 28 polychlorinated biphenyls in capillary gas chromatography referred to 2,4,6-trichlorophenyl alkyl ethers as RI-standards. Fresenius J Anal Chem 348, 595–597 (1994). https://doi.org/10.1007/BF00323939

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  • DOI: https://doi.org/10.1007/BF00323939

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