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Separation of bromide, bromate, iodide, iodate, nitrite, nitrate and selenite anions by capillary zone electrophoresis

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  • Inorganic Analysis
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Summary

Capillary zone electrophoresis (CZE) has been used for the separation of bromide, bromate, iodide, iodate, nitrite, nitrate and selenite anions. The separation was achieved using a fused silica capillary (72 cm long x 50 μm i.d.) filled with an acidic phosphate buffer (pH=3, 25 mmol/l), and with on-column UV detection at 200 nm. The influence of different experimental parameters such as pH, ionic strength and voltage, was studied. The nitrate concentration of a Rhine water sample was then determined under selected conditions and the results were compared to those obtained by high performance ion chromatography (HPIC).

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References

  1. Ewing AG, Wallingford AR, Olefirowicz TM (1989) Anal Chem 61:292A-303A

    Google Scholar 

  2. Gareil P (1990) Analusis 18:221–241

    Google Scholar 

  3. Gareil P (1990) Analusis 18:447–468

    Google Scholar 

  4. Schomburg C (1990) Chromatographia 30:500–508

    Google Scholar 

  5. Kuhr WG (1990) Anal Chem 62:403R-414R

    Google Scholar 

  6. Yeung ES, Kuhr WG (1991) Anal Chem 63:275A-282A

    Google Scholar 

  7. Honda S, Suzuki K, Kakechi K (1989) Anal Biochm 177:62–66

    Google Scholar 

  8. Tsuda T, Nomura K, Nakagawa G (1983) J Chrotogr 264:385–392

    Google Scholar 

  9. Swaile DF, Sepaniak MJ (1991) Anal Chem 63:179–184

    Google Scholar 

  10. Aguilar M, Huang X, Zare RN (1989) J Chromatogr 480:427–431

    Google Scholar 

  11. Yeung ES, Gross L (1990) Anal Chem 62:427

    Google Scholar 

  12. Wallingford AR, Ewing AG (1987) Anal Chem 59:1762–1766

    Google Scholar 

  13. Huang X, Pang TKJ, Gordon MJ, Zare RN (1987) Anal Chem 59:2747–2749

    Google Scholar 

  14. Huang X, Zare RN, Sloss S, Ewing AG (1991) Anal Chem 63:189–192

    Google Scholar 

  15. Huang X, Zare RN (1991) Anal Chem 63:2193–2196

    Google Scholar 

  16. Jorgenson JW, Luckas KD (1983) Science 222:266–272

    Google Scholar 

  17. Lambert, JW, Middleton, DL (1990) Anal Chem 62:1585–1587

    Google Scholar 

  18. Dose EV, Guiochon, GA (1991) Anal Chem 63:1154–1158

    Google Scholar 

  19. Fustec E, Schenck C, Cloots-Hirsch AR, Soulie M, Bouton D, Ackerer P, Pinay G, Tournoud MG (1991) Les nitrates dans les vallées fluviales. Report of CNRS, Paris

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Authors and Affiliations

  1. Laboratoire de Chimie Minérale et Analytique, URA 405 du CNRS, EHICS, 1 rue Blaise Pascal, F-67008, Strasbourg Cedex, France

    M. B. Amran, M. D. Lakkis, F. Lagarde & M. J. F. Leroy

  2. Departament de Quimica Analitica, Universitat de Barcelona, Av. Diagonal 647, E-08028, Barcelona, Spain

    J. F. Lopez-Sanchez & G. Rauret

Authors
  1. M. B. Amran
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  2. M. D. Lakkis
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  3. F. Lagarde
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  4. M. J. F. Leroy
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  5. J. F. Lopez-Sanchez
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  6. G. Rauret
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Additional information

On leave from the Universitat de Barcelona (postdoctoral fellowship from ECC-BCR).

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Amran, M.B., Lakkis, M.D., Lagarde, F. et al. Separation of bromide, bromate, iodide, iodate, nitrite, nitrate and selenite anions by capillary zone electrophoresis. Fresenius J Anal Chem 345, 420–423 (1993). https://doi.org/10.1007/BF00325618

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  • DOI: https://doi.org/10.1007/BF00325618

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