Skip to main content
Log in

The effects of methane-debris molecules on the frictional properties of diamond

  • Published:
Tribology Letters Aims and scope Submit manuscript

Abstract

Molecular dynamics simulations have been used to examine the friction between two surfaces placed in sliding contact. These simulations show that the presence of methane-debris molecules squeezed between two hydrogen-terminated diamond (111) surfaces significantly reduces the friction compared to the same two surfaces in the absence of debris. These findings are in agreement with macroscopic experiments that have examined the friction of diamond on diamond in the presence of debris. In addition, the friction coefficients are significantly lower compared to the same system with methyl groups chemisorbed to one of the diamond surfaces.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. X.Y. Zhu and J.M. White, Surf. Sci. 214 (1989) 240.

    Google Scholar 

  2. M. Tsuda, M. Nakajima and S. Oikawa, J. Am. Chem. Soc. 108 (1986) 5780.

    Google Scholar 

  3. M. Frenklach and H. Wang, Phys. Rev. B 43 (1991) 1520.

    Google Scholar 

  4. D. Huang, M. Frenklach and M. Maroncelli, J. Phys. Chem. 92 (1988) 6379.

    Google Scholar 

  5. D.N. Belton and S.J. Harris, J. Chem. Phys. 96 (1992) 2371.

    Google Scholar 

  6. D.G. Goodwin and G.G. Gavillet, J. Appl. Phys. 68 (1990) 6393.

    Google Scholar 

  7. J. Xing and H.L. Scott, Phys. Rev. B 48 (1993) 4806.

    Google Scholar 

  8. X.Y. Chang, M. Perry, J. Peploski, D.L. Thompson and L.M. Raff, J. Chem. Phys. 99 (1993) 4748.

    Google Scholar 

  9. M.D. Perry and L.M. Raff, J. Phys. Chem. 98 (1994) 4375.

    Google Scholar 

  10. M.D. Perry and L.M. Raff, J. Phys. Chem. 98 (1994) 8128.

    Google Scholar 

  11. Y.-L. Chen and J.N. Israelachvilli, J. Phys. Chem. 96 (1992) 7752.

    Google Scholar 

  12. J.N. Israelachvilli, P.M. McGuiggan and A.M. Homola, Science 240 (1988) 189.

    Google Scholar 

  13. J. Van Alsten and S. Granick, Phys. Rev. Lett. 16 (1991) 33.

    Google Scholar 

  14. S. Granick, Science 283 (1991) 1374.

    Google Scholar 

  15. J. Krim, D.H. Solina and R. Chiarello, Phys. Rev. Lett. 66 (1991) 181.

    Google Scholar 

  16. E.T. Watts, J. Krim and A. Windom, Phys. Rev. B 41 (1990) 3466.

    Google Scholar 

  17. C.M. Mate, G.M. McClelland, R. Erlandsson and S. Chiang, Phys. Rev. Lett. 59 (1987) 1942.

    Google Scholar 

  18. R. Erlandsson, G. Hadziloannou, C.M. Mate, G.M. McClelland and S. Chiang, J. Chem. Phys. 89 (1988) 5190.

    Google Scholar 

  19. C.M. Mate, Wear 168 (1993) 17.

    Google Scholar 

  20. E. Meyer, R. Overney, D. Brodbeck, L. Howald, R. Luthi, J. Frommer and H.-J. Guntherodt, Phys. Rev. Lett. 69 (1992) 1777.

    Google Scholar 

  21. E. Meyer, R. Overney, R. Luthi, D. Brodbeck, L. Howald, J. Frommer, H.-J. Guntherodt, O. Wolter, M. Fujihira, H. Takano and Y. Gotoh, Thin Solid Films 220 (1992) 132.

    Google Scholar 

  22. G.J. German, S.R. Cohen, G. Neubauer, G.M. McClelland, H. Seki and D. Coulman, J. Appl. Phys. 73 (1993) 163.

    Google Scholar 

  23. G.A. Tomlinson, Phil. Mag. Ser. 7 (1929) 905.

    Google Scholar 

  24. F.C. Frenkel and T. Kontorova, Zh. Eksp. Teor. Fiz. 8 (1938) 1340.

    Google Scholar 

  25. M. Hirano and K. Shinjo, Phys. Rev. B 41 (1984) 11837.

    Google Scholar 

  26. M. Hirano, K. Shinjo, R. Kaneko and R. Murata, Phys. Rev. Lett. 67 (1991) 2642.

    Google Scholar 

  27. J.B. Sokoloff, Surf. Sci. 144 (1984) 267.

    Google Scholar 

  28. J.B. Sokoloff, Phys. Rev. B 42 (1990) 760.

    Google Scholar 

  29. W. Zhong and D. Tomanek, Phys. Rev. Lett. 64 (1990) 3054.

    Google Scholar 

  30. G.M. McClelland and J.N. Glosli, in: Fundamentals of Friction: Macroscopic and Microscopic Processes, NATO ASI Proceedings, eds. I.L. Singer and H.M. Pollock (Kluwer, Dordrecht, 1992) pp. 405–426.

    Google Scholar 

  31. U. Landman and W.D. Luedtke, J. Vac. Sci. Technol. B 9 (1991) 414.

    Google Scholar 

  32. P.A. Thompson and M.O. Robbins, Phys. Rev. Lett. 63 (1989) 766.

    Google Scholar 

  33. P.A. Thompson and M.O. Robbins, Science 250 (1990) 792.

    Google Scholar 

  34. J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, Phys. Rev. B 46 (1992) 9700.

    Google Scholar 

  35. J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, Wear 168 (1993) 127.

    Google Scholar 

  36. J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, J. Phys. Chem. 97 (1993) 6573.

    Google Scholar 

  37. J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, Thin Solid Films 260 (1995) 205.

    Google Scholar 

  38. M.D. Perry and J.A. Harrison, J. Phys. Chem. 99 (1995) 9960.

    Google Scholar 

  39. J.A. Harrison, C.T. White, R.J. Colton and D.W. Brenner, J. Am. Chem. Soc. 116 (1994) 10399.

    Google Scholar 

  40. I.P. Hayward and J.E. Field, Proc. Inst. Mech. Eng., IMechE Conf. 1 (1987) 205.

    Google Scholar 

  41. D.W. Brenner, Phys. Rev. B 42 (1990) 9458; D.W. Brenner, J.A. Harrison, C.T. White and R.J. Colton, Thin Solid Films 206 (1991) 220.

    Google Scholar 

  42. C.W. Gear, Numerical Initial Value Problem in Ordinary Differential Equations (Prentice-Hall, Englewood Cliffs, 1971).

    Google Scholar 

  43. H.J.C. Berendsen, J.P.M. Postma, W.F. van Gunsteren, A. DiNola and J.R. Haak, J. Chem. Phys. 81 (1984) 3684.

    Google Scholar 

  44. W.B. Hardy and I. Doubleday, Proc. Roy. Soc. A 101 (1922) 487; 100 (1922) 550; 104 (1923) 25.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Perry, M.D., Harrison, J.A. The effects of methane-debris molecules on the frictional properties of diamond. Tribol Lett 1, 109–119 (1995). https://doi.org/10.1007/BF00209766

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00209766

Keywords

Navigation