Abstract
The thermal stability of the Wells–Dawson heteropoly compound K6P2W18O62·10H2O was examined under both reducing and oxidizing conditions, and its structural and morphological evolution was characterized by several complementary solid state techniques. It is shown that the primary structure of the title compound remains intact up to 770 K, while at higher temperature structural changes and rearrangements are observed. These modifications depend considerably on the treatment conditions and catalyst composition. Under oxidizing conditions the Wells–Dawson compound rearranges with formation of a mixed phase containing the Keggin-type unit K3PW12O40 and the hexatungstate K2W6O19. Furthermore, the catalytic activity in the oxidation of isobutane is affected considerably by these changes. The best catalytic performance was shown by the rearranged Wells–Dawson compound.
Similar content being viewed by others
References
M. Misono, Stud. Surf. Sci. Catal.75 (1993) 69.
M. Misono, Catal. Rev. Sci. Eng. 29 (1987) 269.
C.L. Hill and C.M. Prosser-Mc Cartha, Coord. Chem. Rev. 143 (1995) 407.
Y. Wu, S. Qu, H. Ma and S. Ya, Catal. Lett. 23 (1994) 195.
F. Cavani, C. Comuzzi, G. Dolcetti, E. Etienne, R.G. Finke, G. Selleri, F. Trifirò and A. Trovarelli, J. Catal. 160 (1996) 317.
D.J. Edlund, R.J. Saxton, D.K. Lyon and R.G. Finke, Organometallics 7 (1988) 1692.
H. Hayashi and J.B. Moffat, J. Catal. 77 (1982) 473.
Y. Konishi, K. Sakata, M. Misono and Y. Yoneda, J. Catal. 77 (1982) 169.
M.T. Pope, Heteropoly and Isopoly Oxometalates (Springer, New York, 1983).
J.B. Black, N.J. Clayden, P.L. Gay, J.D. Scott, E.M. Serwicka and J.B. Goodenough, J. Catal. 106 (1987) 1.
H. Hayashi and J.B. Moffat, J. Catal. 83 (1983) 192.
M.T. Pope and A. Muller, Angew. Chem. Int. Ed. Engl. 30 (1991) 34.
K. Bruckman and J. Haber, in: Advances in Catalyst Design,eds. C.N.R. Rao and M. Graziani (World Scientific, Singapore, 1993) p. 111.
C. Comuzzi, G. Dolcetti, A. Trovarelli, F. Cavani, F. Trifirò, J. Llorca and R.G. Finke, Catal. Lett. 36 (1996) 75.
U.B. Mioc, R.Z. Dimitrijevic, M. Davidovic, Z.P. Nedic, M.M. Mitrovic and P.H. Colomban, J. Mater. Sci. 29 (1994) 3705.
Y. Takita, K. Kurosaki, Y. Mizuhara and T. Ishihara, Chem. Lett. (1993) 335.
P.M. Michalakos, M.C. Kung, I. Jahan and H.H. Kung, J. Catal. 140 (1993) 226.
D. Patel, M.C. Kung and H.H. Kung, in: Proc.9th Int.Congress on Catalysis, Vol. 4, Calgary (1988) p. 1554.
W. Zhang, D.L. Tang, X.P. Zhou, H.L. Wan and K.R. Tsai, J. Chem. Soc., Chem. Comm. 771 (1994).
F. Cavani, E. Etienne, M. Favaro, A. Galli, F. Trifirò and G. Hecquet, Catal. Lett. 32 (1995) 215.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Comuzzi, C., Primavera, A., Trovarelli, A. et al. This paper was incompletely published in Topics in Catalysis Volume 3 (1996) pp. 387–406. The complete version is printed below.. Topics in Catalysis 9, 251–262 (1999). https://doi.org/10.1023/A:1019187211613
Issue Date:
DOI: https://doi.org/10.1023/A:1019187211613