Abstract
The topic is discussed in relation to the definition of activators, which are classified in accordance with their mode of action; particular attention is given to orienting and polarizing effects, activated electron transfer, formation of intermediate compounds, and displacement of equilibria in intermediate stages. Criteria are proposed for assigning activators to these four groups.
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K. B. Yatsimirskii and V. E. Kalinina, Zh. Neorg. Khimii, 9, 1328, 1964.
J. V. Rund and R. A. Plane, J. Am. Chem. Soc., 86, 367, 1964.
K. B. Yatsimirskii and L. P. Alfanas'eva, Zh. Analit. Khim., 11, 319, 1956.
K. B. Yatsimirskii and V. I. Rigin, Zh. Analit. Khim., 13, 112, 1958.
K. B. Yatsimirskii, O. N. Drobysheva, and V. I. Rigin, Zh. Analit. Khim., 14, 60, 1959.
K. B. Yatsimirskii and I. I. Alekseeva, Zav. Lab., 24, 1427, 1958.
K. B. Yatsimirskii and Yu. A. Zhukov, Radiokhimiya, 3, 466, 1961.
K. B. Yatsimirskii and G. A. Karacheva, Zh. Neorg. Khim., 3, 352, 1958.
K. B. Yatsimirskii and L. P. Raizman, Zh. Neorg. Khim., 5, 593, 1961.
K. B. Yatsimirskii and L. P. Raizman, Zh. Neorg. Khim., 7, 1819, 1962.
K. B. Yatsimirskii and V. I. Skuratov, Zh. Neorg. Khim., 8, 573, 1963.
K. B. Yatsimirskii, Pure Appl. Chem., 6, 117, 1963.
K. B. Yatsimirskii, Kinetika i Kataliz (in press).
M. T. Beck and I. Gymesi, Mag. Kem. Foly., 69, 552, 1963.
R. Courtney, R. Gustafson, S. Westerback, H. Hyytiainen, S. Chaberek, and A. Martell, J. Am. Chem. Soc., 79, 3030, 1957.
A. Kornberg, S. Ochoa, and A. H. Mehler, J. Biol. Chem., 174, 159, 1948.
H. Taube, J. Am. Chem. Soc., 77, 4481, 1955.
H. Taube, Canad. J. Chem., 37, 129, 1959.
D. K. Sebera and H. Taube, J. Am. Chem. Soc., 83, 1785, 1961.
J. H. Wang, J. Am. Chem. Soc., 77, 822, 4715, 1955.
A. E. Martell, Reactions of Coord. Ligands and Homog. Catalysis, Adv. Chem. Ser. no. 37, p. 161, Washington, 1963.
R. Myer and A. Zettelemogers, Ind. Eng. Chem., 46, 2220, 1954.
E. Tanner, W. Schuler, and R. Meier, Helv. Chim. Acta, 42, 445, 1959.
R. L. Gustafson and A. E. Martell, J. Am. Chem. Soc., 84, 2309, 1962.
R. L. Gustafson, S. Chaberek and A. E. Martell, J. Am. Chem. Soc., 85, 598, 1963.
R. Hofstetter, Y. Murakami, G. Mont, and A. E. Martell, J. Am. Chem. Soc., 84, 3041, 1962.
T. Wagner-Jauregg, B. E. Hackley, Jr., T. A. Lies, O. O. Owens, and R. Proper, J. Am. Chem. Soc., 77, 922, 1955.
R. Kuhn and A. Wassermann, Ann., 503, 203, 1933.
W. G. Barb, J. H. Baxendale, P. George, and K. R. Hargrave, Trans. Faraday Soc., 51, 935, 1955.
F. M. Fowkes, G. S. Ronay, and B. L. Ryland, J. Phys. Chem., 62, 867, 1958.
J. E. Prue, J. Chem. Soc., 2331, 1952.
G. Wada, T. Nakamura, K. Terauchi, and T. Nakai, Bull. Chem. Soc. Japan, 37, 447, 1964.
A. Albert, Strategy in Chemotherapy [Russian translation], Izd. In. Lit., Moscow, p. 135, 1960.
H. Ojima, J. Chem. Soc. Japan, Pure Chem. Sec., 80, 965, 1371, 1959.
H. Ojima, J. Chem. Soc. Japan, Pure Chem. Soc., 81, 1785, 1960
R. Hofstetter and A. E. Martell, J. Am. Chem. Soc., 81, 4461, 1959.
Z. Kováts, Mag. Kém. Foly., 69, 98, 1963.
L. A. Nikolaev, Usp. Khimii, 30, 313, 1961.
A. B. Fasman, V. A. Golodov, and D. V. Sokol'skii, Zh. Fiz. Khim., 38, 1545, 1964.
L. A. Nikolaev and A. P. Sychev, Nauch. Dokl. Vyssh. Shkoly, Khim. i Khim. Tehknol., no. 1, 89, 1958.
L. A. Nikolaev, Kinetika i Kataliz, 1, 94, 1960.
H. Ojima and K. Sone, Bull. Chem. Soc. Japan, 35, 298, 1962.
T. Iwasaki, J. Chem. Soc. Japan, 63, 820, 1942; C. A. 41, 2975, 1947.
K. I. Matveev, A. M. Osipov, V. F. Odyakov, Yu. V. Suzal'nitskaya, I. F. Bukhtoyarov, and O. A. Emel'yanova, Collection: Liquid-Phase Catalyzed Reactions [in Russian], Alma Alta, Akad. Nauk KazSSR, p. 371, 1963.
R. D. P. Williams, Transactions of the 5th International Biochemical Congress, Symposium 4, Izd. AN SSSR, Moscow, p. 161, 1962.
L. A. Nikolaev, Zh. Fiz. Khim., 31, 1185, 1957.
L. A. Nikolaev, Vestnik AN SSSR, no. 3, 13, 1960.
H. Taube, Adv. Inorg. Chem. Radiochem., Acad. Press Inc., N. Y., 1959.
R. T. M. Fraser, J. Am. Chem. Soc., 83, 564, 1961.
R. T. M. Fraser, J. Am. Chem. Soc., 83, 4920, 1961.
P. R. Bonchev and K. B. Yatsimirskii, Zh. Fiz. Khim. (in press).
R. M. Milburn and H. Taube, J. Phys. Chem., 64, 1756, 1960.
J. Halpern and L. E. Orgel, Discuss. Faraday Soc., 29, 32, 1960.
D. K. Sebera and H. Taube, J. Am. Chem. Soc., 83, 1785, 1961.
E. S. Gould and H. Taube, J. Am. Chem. Soc., 85, 3706, 1963.
R. T. M. Fraser and H. Taube, J. Am. Chem. Soc., 83, 2239, 1961.
R. T. M. Fraser and H. Taube, J. Am. Chem. Soc., 81, 5514, 1959.
P. Saffir and H. Taube, J. Am. Chem. Soc., 82, 13, 1960.
W. F. Libby, J. Phys. Chem., 56, 863, 1952.
A. P. Terent'ev and Ya. D. Mogilyanskii, Zh. Obshch. Khim., 28, 1959, 1958.
A. P. Terent'ev and Ya. D. Mogilyanskii, Zh. Obshch. Khim., 31, 326, 1961.
A. V. Gorbunova, M. L. Khidikel, and G. A. Razuvaev, DAN SSSR, 147, 368, 1962.
K. Kinoshita, Bull. Chem. Soc. Japan, 32, 777, 780, 783, 1959.
A. P. Terent'ev and Ya. D. Mogilyanskii, DAN SSSR, 103, 91, 1955.
I. Szeredy, Dissertation, Univ. P. P. Budapest, 1939; cited by J. Bognár, Freiberg, Forschungsh. c. 103, Acad. Verlag, Berlin, 1962.
H. Euler and B. Jansson, Monatsh., 53/54, 1014, 1929.
L. Erdey, Kém. Lapja, 3, 45, 1942; C. A. 38, 6227, 1944.
M. M. Raines and Yu. A. Larionov, Trudy Kom. Anal. Khim., 7, 295, 1956.
R. D. Korpusova and L. A. Nikolaev, Nauch. Dokl. Vyssh. Shkoly, Khim. i Khim. Tekhnol., no. 2, 233, 1958.
I. F. Dobmanova and V. M. Peshkova, Zh. Analit. Khim., 19, 297, 1964.
W. K. Wilmarth and M. K. Barsh, J. Am. Chem. Soc., 75, 2237, 1953.
W. K. Wilmarth, and A. F. Kapauan, J. Am. Chem. Soc., 78, 1308, 1956.
M. Calvin, J. Am. Chem. Soc., 61, 2230, 1939.
H. L. SchlÄfer and E. Konig, Z. Physik. Chem., 30, 143, 1961.
L. Szebellédy and M. Ajtai, Mikrochem., 26, 72, 1939.
J. Bognár and O. Jellinek, Mag. Kém. Foly., 67, 73, 1961.
J. Bognár and O. Jellinek, Mag. Kém. Foly., 67, 100, 1961.
J. Bognár and O. Jellinek, Mag. Kém. Foly., 67, 103, 1961.
J. Bognár, Mikrochim. Acta, Mikrochim. Acta, 577, 1962.
P. R. Bontschev, Mikrochim. Acta, 577, 1962.
P. R. Bontschev, Mikrochim. Acta, 584, 1962.
M. Bobtelsky and B. Kirson, Compt. rend., 199, 573, 1934.
N. Uri, J. Phys. Colloid. Chem., 53, 1070, 1949.
R. Resnik, T. Cohen, and Q. Fernando, J. Am. Chem. Soc., 83, 3341, 1961.
T. Braun, Rev. de Chimie, 8, 43, 1957.
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Bonchev, P.R., Yatsimirskii, K.B. Activation in homogeneous catalysis. Theor Exp Chem 1, 113–119 (1965). https://doi.org/10.1007/BF00945569
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DOI: https://doi.org/10.1007/BF00945569