Skip to main content
Log in

Rutherford-backscattering study of high-temperature oxidation of Y-implanted Fe-24Cr

  • Published:
Oxidation of Metals Aims and scope Submit manuscript

Abstract

We have investigated the effect of Y ion implantation on the high-Temperature oxidation of Fe-24Cr using Rutherford-backscattering spectroscopy, secondary ion mass spectroscopy, and analytical electron microscopy. Results indicate that implantation of Y has a very large effect on the growth rate of the oxide compared to metals alloyed with Y. Analytical tools have been applied to determine the spatial distribution of Y, the microstructure of the oxide, and contribution of oxygen transport to the oxidation process. Results are compared with those of recent cation-diffusion measurements in Cr2O3 and Cr2O3 doped with Y2O3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. S. Grabowski and L. E. Rehn, inCorrosion of Metals Processed by Directed Energy Beams, C. R. Clayton and C. M. Preece, eds. (Metallurgical Society of AIME, (1981), p. 23.

  2. G. Dearnaley,Nucl. Instrum. Methods 182/183, 899 (1981).

    Google Scholar 

  3. G. Dearnaley, inTreatise on Materials Science and Technology, Vol. 18, (1980), p. 257.

  4. M. J. Bennett inHigh Temperature Corrosion, NACE-6 (1983), p. 145.

  5. Clive R. Clayton inSurface Alloying by Ion, Electron, and Laser Beams L. E. Rehn, S. T. Picraux, and H. Wiedersich, eds. (ASM, Metals Park, Ohio, 1987), p. 325.

    Google Scholar 

  6. J. E. Antill, M. J. Bennett, R. F. A. Carney, G. Dearnaley, F. H. Fern, P. D. Goode, B. L. Myatt, J. F. Turner, and J. B. Warburton,Corr. Sci. 16, 729 (1976).

    Google Scholar 

  7. M. J. Bennett, G. Dearnaley, M. R. Houlton, R. W. M. Hawes, P. D. Goode, and M. A. Wilkins,Corr. Sci. 20, 73 (1980).

    Google Scholar 

  8. M. J. Bennett, G. Dearnaley, M. R. Houlton, and R. W. M. Hawes, inIon Implantation into Metals, V. Ashworth, W. A. Grant, R. P. M. Procter, eds. (Pergamon Press, London, 1982), p. 264.

    Google Scholar 

  9. M. J. Bennett, B. A. Bellamy, G. Dearnaley, and M. R. Houlton inProceedings of the Ninth International Congress on Metallic Corrosion Vol. 2, (1984), p. 416.

  10. U. Bernabai and M. Cavallini,Surface Technol. 7, 289 (1978).

    Google Scholar 

  11. M. Slater, W. A. Grant, and G. Carter,Radiat. Effects 82, 239 (1984).

    Google Scholar 

  12. M. Slater,Radiat. Effects 82, 249 (1984).

    Google Scholar 

  13. R. A. Collins, S. Muhl, and G. Dearnaley,J. Phys. F: Metal Phys. 9, 1245 (1979).

    Google Scholar 

  14. R. A. Collins, S. Muhl, and G. Dearnaley,Philos. Trans. Roy. Soc. Lond. A295, 331 (1980).

    Google Scholar 

  15. J. C. Pivan, D. Delaunay, C. Roques-Carmes, A. M. Huntz, and P. Lacombe,Corr. Sci. 20, 351 (1980).

    Google Scholar 

  16. J. Pivan and D. Loison,J. Phys. Colloq. 45, 647 (1984).

    Google Scholar 

  17. J. C. Pivan, C. Roques-Carmes, J. Chaumont, and H. Bernas,Corr. Sci. 20, 947 (1980).

    Google Scholar 

  18. K. Przybylski, A. J. Garratt-Reed, and G. J. Yurek,J. Am. Ceram. Soc. 69, (11) C264–266 (1986).

    Google Scholar 

  19. R. O. Bondelid and E. E. Dowling Whiting,Phys. Rev. 134B, 591 (1964).

    Google Scholar 

  20. J. F. Ziegler, P. F. Lever, and J. K. Houover, inIon Beam Surface Layer Analysis, O. Mayer, G. Linden, and F. Kappler, eds. (Plenum, New York, 1976), Vol. 1, p. 163.

    Google Scholar 

  21. J. J. Morè, B. S. Garbow, and K. E. Hillstrom, User Guide for MINPACK-1, Argonne National Laboratory Report No. ANL-80-74 (1980).

  22. Jorge J. Morè, inLecture Notes in Mathematics (Springer-Verlag, Berlin, 1978), p. 105.

    Google Scholar 

  23. S. Matsunaga and T. Homma,Oxid. Met. 10, 361 (1976).

    Google Scholar 

  24. C. Wagner,Z. Phys. Chem. B21, 25 (1933).

    Google Scholar 

  25. M. J. Graham, J. I. Eldridge, D. F. Mitchell, and R. J. Hussey,Mater. Sci. Forum (submitted).

  26. E. W. Hart,Acta Met. 5, 597 (1957).

    Google Scholar 

  27. A. Atkinson and R. I. Taylor, inTransport in Nonstoichiometric Oxides, G. Simkovich and V. S. Stubican, eds., NATO ASI Series B129, 385 (1984), p. 285.

  28. H. Hindam and D. P. Whittle,Oxid. Met. 18, 245 (1982).

    Google Scholar 

  29. C. M. Cotell, K. Przybylski, and G. J. Yurek, inAbstracts from the One Hundred and Sixty-Ninth Meeting of the Electrochemical Society, Boston, May 4–9, 1986, p. 116C, abst. 364.

  30. K. P. Lillerud and P. Kofstad,Oxid. Met. 17, 127 (1982).

    Google Scholar 

  31. D. Caplan and I. Sproule,Oxid. Met. 5, 459 (1975).

    Google Scholar 

  32. J. H. Park, Wayne E. King, and S. J. Rothman,J. Am. Ceram. Soc. 70, 880 (1987).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

King, W.E., Grabowski, K.S., Mitchell, D.F. et al. Rutherford-backscattering study of high-temperature oxidation of Y-implanted Fe-24Cr. Oxid Met 31, 181–207 (1989). https://doi.org/10.1007/BF00846686

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00846686

Key words

Navigation