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Heat capacities and densities of mixtures of very polar substances. 3. Mixtures containing either trichloromethane or 1,4-dioxane or diisopropylether

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Abstract

Excess molar heat capacities C E P at constant pressure and excess molar volumes VE have been determined, as a function of mole fraction x1 at 25°C and atmospheric pressure, for 10 binary liquid mixtures containing either trichloromethane (series I) with C6H5CH3, or C6H5Cl, or C5H5N, or CH3COCH3, or C6H5NO2; 1,4-dioxane (series II) with (C2H5)3N, or (CH3)2CHOCH(CH3)2, or (CH3 2SO); or diisopropyl ether (di-1-methylethyl ether) (series III) with (C2H5)3N, or CHCl3. The dipole momentsp (10−30C-m) of the substances range from nearly 0 to 14.1 for nitrobenzene. The C E P of series I and III are all positive, with C E P (x1=0.5) (J-K−1-mol−1) ranging from 1.04 for {x1CHCl3+x2C6H5Cl} to 16.66 for {x1(CH3)2CHOCH(CH3)2+x2CHCl3}. In series II, the C E P are positive and small for {x11,4-C4H8O2+x2(CH3)2CHOCH(CH3)2}, S-shaped and small for {x11,4-C4H8O2+x2(C2H5)3N}, and negative and small for {x11,4-C4H8O2+x2(CH3)2SO}. The excess volumes are small and positive for {x1CHCl3+x2C6H5CH3}, S-shaped for {x1CHCl3+x2CH3COCH3}, {x11,4-C4H8O2+x2(C2H5)3N} and {x1(CH3)2CHOCH(CH3)2+x2(C2H5)3N}, and negative for the other systems.

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Authors and Affiliations

  1. Laboratoire de Thermodynamique et Génie Chimique, Université Blaise Pascal, F-63177, Aubière, France

    J. -P. E. Grolier, G. Roux-Desgranges & M. Berkane

  2. Institut fär Physikalische Chemie, Universität Wien, Währingerstrasse 42, A-1090, Wien, Austria

    Emmerich Wilhelm

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  1. J. -P. E. Grolier
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  2. G. Roux-Desgranges
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  3. M. Berkane
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  4. Emmerich Wilhelm
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Grolier, J.P.E., Roux-Desgranges, G., Berkane, M. et al. Heat capacities and densities of mixtures of very polar substances. 3. Mixtures containing either trichloromethane or 1,4-dioxane or diisopropylether. J Solution Chem 23, 153–166 (1994). https://doi.org/10.1007/BF00973543

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