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A palladium(II) complex of a tetradentate amine-phenol ligand

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Abstract

A palladium(II) complex of an amine-phenol ligand N,N′-bis(2-hydroxybenzyl)1,4-diaminobutane has been synthesized and characterized by NMR, IR, and X-ray diffraction studies. Diffraction data were collected with a Nonius CAD-4 diffractometer with θ-2θ scan and MoKα radiation. The structure was solved by conventional methods resulting in anR factor of 0.022 for 1058 independent reflections. The X-ray structure shows a discrete mononuclear square planar complex in which the Pd is coordinated to the two nitrogens and two oxygens of the ligand. The complex is neutral with the Pd(II) charge balanced by deprotonation of both phenolic oxygens. Crystal data: Space group Pna21,a+8.223 Å,b+22.477 Å,c+9.190 Å;V+1698.8 Å3;Z+4.

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Author notes

  1. M. R. A. Pillai

    Present address: Isotope Division, Bhabha Atomic Research Centre, 400 085, Bombay, India

Authors and Affiliations

  1. Department of Chemistry, University of Missouri-Columbia, 65211, Columbia, Missouri

    M. R. A. Pillai & E. O. Schlemper

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  1. M. R. A. Pillai
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  2. E. O. Schlemper
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Pillai, M.R.A., Schlemper, E.O. A palladium(II) complex of a tetradentate amine-phenol ligand. J Chem Crystallogr 24, 129–132 (1994). https://doi.org/10.1007/BF01833668

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  • DOI: https://doi.org/10.1007/BF01833668

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