Skip to main content
SpringerLink
Log in

Structure and IR, UV spectroscopic behavior of azabicyclo[2.2.2]octane pentachlorophenolate

  • Published:
Journal of Crystallographic and Spectroscopic Research Aims and scope Submit manuscript

Abstract

The structure of C6Cl5O−·C7H13NH+ has been determined by X-ray diffraction. The crystals are orthorhombic:Pcab,a=10.706(1),b=11.966(2),c=24.913(5)Å,Z=8. The structure was solved by direct methods, and refined to R=0.042 for 1523 nonzero reflections. The N+-H⋯O− hydrogen bond is shortened (2.553(5)Å) and deformed (<NHO=164(4)°, <CON=137.0(3)°). IR and UV spectra indicate the ionic character of the complex and a moderately strong hydrogen bond.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Cremer, D., and Pople, J. A. (1975)J. Am. Chem. Soc. 97, 1354.

    Google Scholar 

  • Dega-Szafran Z., Hrynio A., and Szafran. M. (1987)Spectrochim. Acta 43A, 1553.

    Google Scholar 

  • Fried F., and Brot C., (1974)Mol. Phys. 27, 1701.

    Google Scholar 

  • Grech E., Kalenik J., and Sobczyk L., (1979)J. Chem. Soc. Faraday Trans. I 75, 1587.

    Google Scholar 

  • Huyskens P., and Zeegers-Huyskens T. (1964)J. Chim. Phys. 61, 81.

    Google Scholar 

  • International Tables for X-ray Crystallography (1974) Vol. IV, Kynoch Press, Birmingham.

  • Lassier B., and Brot C., (1974)Mol. Phys. 27, 1697.

    Google Scholar 

  • Majerz I., Malarski Z., and Lis T. (1989a)J. Cryst. Spectr. Res. 19, 349.

    Google Scholar 

  • Majerz I., Malarski Z., and Lis T. (1989b)J. Mol. Struct. 213, 161.

    Google Scholar 

  • Majerz I., Malarski Z., and Lis T. (1991a)J. Mol. Struct. 243, 351.

    Google Scholar 

  • Majerz I., Malarski Z., and Sawka-Dobrowolska W. (1991)J. Mol. Struct. 249, 109.

    Google Scholar 

  • Malarski Z., Majerz I., and Lis T. (1987a)Acta Crystallogr. C 43, 1766.

    Google Scholar 

  • Malarski Z., Majerz I., and Lis T. (1987b)J. Mol. Struct. 158, 369.

    Google Scholar 

  • Malarski Z., Rospenk M., Sobczyk I., and Grech E. (1986)J. Phys. Chem. 86, 401.

    Google Scholar 

  • Nouwen R., and Huyskens P. (1973)J. Mol. Struct. 16, 459.

    Google Scholar 

  • Ratajczak H., and Sobczyk L. (1969)J. Chem. Phys. 50, 262.

    Google Scholar 

  • Sheldrick, M. (1986)Shelx 86,Program for the solution of crystal structure. (Univ. of Gottingen).

  • Syntex XTL/XTLE Structure Determination System (1976) Syntex Analytical Instruments, Cupertino, CA.

  • Walker N., and Stuart D. (1983)Acta Crystallogr. A 39, 158.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383, Wrocław, Poland

    I. Majerz, Z. Malarski & W. Sawka-Dobrowolska

Authors
  1. I. Majerz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. Malarski
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. W. Sawka-Dobrowolska
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Majerz, I., Malarski, Z. & Sawka-Dobrowolska, W. Structure and IR, UV spectroscopic behavior of azabicyclo[2.2.2]octane pentachlorophenolate. Journal of Crystallographic and Spectroscopic Research 23, 555–561 (1993). https://doi.org/10.1007/BF01228764

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01228764

Keywords

Search

Navigation