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Structural and spectral studies of di-(triphenylmethylium-hexachloroantimonate)-benzenesolvate

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Abstract

The crystal structure of (SbCl6C(C6H5)3)2·C6H6 has been determined. It belongs to space groupP21/c , witha=1.765(4),b=.8167(8),c=1.886(3) nm,β=115.81(3)° andZ=4. We found a host/guest structure with benzene as a guest molecule. The SbCl6 octahedrons are distorted toC 4v -symmetry and are arranged in chains alongb, with a charge transfer between them. The propeller structure of the triphenylmethylium is discussed. The distances Cmeth-Cphen are about 0.01 nm shorter than in triphenylmethanes. The IR-spectra of SbCl6 in the crystalline state and in solution are recorded and discussed.

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Authors and Affiliations

  1. Sektion Chemie der Friedrich-Schiller-Universität, Steiger 3, DDR-69, Jena, Germany

    J. Krauße, G. Heublein & G. Rudakoff

  2. Zentralinstitut für Physikaliche Chemie der AdW, Rudower Chousse 5, DDR-1199, Berlin, Germany

    P. Leibnitz

  3. Zentralinstitut für Molekularbiologie der AdW, Robert-Rössle-Str.10, DDR-1115, Berlin, Germany

    G. Reck

Authors
  1. J. Krauße
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  2. G. Heublein
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  3. G. Rudakoff
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  4. P. Leibnitz
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  5. G. Reck
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professor G. Heublein died in 1989.

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Krauße, J., Heublein, G., Rudakoff, G. et al. Structural and spectral studies of di-(triphenylmethylium-hexachloroantimonate)-benzenesolvate. Journal of Crystallographic and Spectroscopic Research 21, 45–49 (1991). https://doi.org/10.1007/BF01158973

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  • DOI: https://doi.org/10.1007/BF01158973

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