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1,3,2,5-Dioxadiphosphorinanes. Six-membered ring compounds containing two different phosphorus atoms

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Abstract

The reaction of bis(hydroxymethyl)phenylphosphane withtert-butyldichlorophosphane leads to the formation ofcis-2-tert-butyl-5-phenyl-1,3,2,5-dioxadiphosphorinane (1). Thecis configuration was definitively proven by the X-ray diffraction study of the 2, 5-dithioxo derivative (2), which was obtained from (1) by a stereoselective reaction. The diselenoxo compound (3) was also prepared. These three new compounds were subjected to a complete NMR study (1H,13C,31P, and77Se).

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Authors and Affiliations

  1. Sektion Chemie der Martin-Luther-Universität, 4020 Halle/S, Weinbergweg 16, Democratic Republic of Germany

    A. Tzschach, K. Jurkschat, A. Zschunke, C. Mügge & B. Altenbrunn

  2. Laboratoire de Chimie Organique E. P. (C. P. 165), Université Libre de Bruxelles, 50, Avenue F. D. Roosevelt, B-1050, Bruxelles, Belgium

    C. Piccinni-Leopardi

  3. Laboratoire de Chimie Physique et de Cristallographie, Université de Louvain, 1, Place Louis Pasteur, B-1348, Louvain-la-Neuve, Belgium

    G. Germain, J. P. Declercq & M. Van Meerssche

Authors
  1. A. Tzschach
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  2. K. Jurkschat
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  3. A. Zschunke
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  4. C. Mügge
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  5. B. Altenbrunn
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  6. C. Piccinni-Leopardi
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  7. G. Germain
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  8. J. P. Declercq
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  9. M. Van Meerssche
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Tzschach, A., Jurkschat, K., Zschunke, A. et al. 1,3,2,5-Dioxadiphosphorinanes. Six-membered ring compounds containing two different phosphorus atoms. Journal of Crystallographic and Spectroscopic Research 15, 423–431 (1985). https://doi.org/10.1007/BF01171046

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  • DOI: https://doi.org/10.1007/BF01171046

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