Abstract
Measured and derived thermophysical properties ofm-cresol are reported for pressures up to 400 MPa at temperatures from 303 to 503 K. Isobaric thermal expansivities were measured by pressure-scanning calorimetry from 303 to 503 K and 0.1 to 400 MPa. The specific volume at 353 K was determined by pycnometry at atmospheric pressure and calculated from isothermal compressibilities measured as a funtion of pressure up to 400 MPa. Specific volumes at other temperatures and pressures are calculated from isothermal compressibilities measured as a function of pressure up to 400 MPa. Specific volumes, isothermal compressibilities, thermal coefficients of pressure, and isobaric and isochoric heat capacities at pressures up to 400 MPa are derived at several temperatures. The effects of pressure on the isobaric heat capacities ofm-cresol,n-hexane, and water are compared. The effects of self-association ofm-cresol are apparent in both the thermal expansivity and the heat capacity data.
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S. L. Randzio, J.-P. E. Grolier, J. R. Quint, D. J. Eatough, E. A. Lewis, and L. D. Hansen,Int. J. Thermophys. 15:415 (1994).
E. M. Woolley, J. G. Travers, B. O. Erno, and L. G. Hepler,J. Phys. Chem. 76:3591 (1971).
J. N. Spencer, C. L. Campanella, E. M. Harris, and W. S. Wolbach,J. Phys. Chem. 89:1888 (1985),
J. N. Spencer, J. A. Andrefsky, J. Naghdi, L. Patti, and J. F. Tarder,J. Phys. Chem. 91:2959 (1987).
J. N. Spencer, K. N. Allot, S. Chanandin, B. G. Enders, A. Grushow, S. P. Kneizys, D. Mobley, J. Naghdi, L. M. Patti, and J. S. Salata,J. Solut. Chem. 17:287 (1988).
C. M. White, F. K. Schweighardt, and J. Shultz,Fuel Process. Technol. 1:209 (1978).
C. M. White and N. C. Li,Anal. Chem. 54:1570 (1982).
C. M. White, L. Jones, and N. C. Li,Fuel 62:1397 (1983).
G. D. Mohr, M. Mohr, A. J. Kidnay, and V. F. Yesavage,J. Chem. Thermodyn. 15:425 (1983).
D. J. Eatough, S. L. Wolfley, L. J. Dungan, E. A. Lewis, and L. D. Hansen,J. Energy Fuels 1:94 (1987).
A. Oikawa and M. Ito,J. Mol. Spectrosc. 126:133 (1985).
H. Mizuno, K. Okuyama, T. Ebata, and M. Ito,J. Phys. Chem. 91:5589 (1987).
S. L. Randzio, D. J. Eatough, E. A. Lewis, and L. D. Hansen,J. Chem. Thermodyn. 20:937 (1988).
L. Ter Minassian and Ph. Pruzan,J. Chem. Thermodyn. 9:375 (1977).
S. L. Randzio and J. Zaslona, Polish Patent 285871.
S. L. Randzio, J.-P. E. Grolier, and J. R. Quint,Rev. Sci. Instrum. 65:960 (1994).
S. L. Randzio,Phys. Lett. A 117:1473 (1986).
K. F. Goldblum, R. W. Martin, and R. B. Young,Ind. Eng. Chem. 39:1471 (1947).
P. Nasir, S. C. Hwang, and R. Kobayashi,J. Chem. Eng. Data 25:298 (1980).
D. H. Krevor, F. W. Lam, and J. M. Prausnitz,J. Chem. Eng. Data 31:353 (1986).
V. G. Niesen and V. F. Yesavage,J. Chem. Eng. Data 33:138 (1988).
TRC Thermodynamic Tables,Nonhydrocarbons 8:Vc-640.
S. L. Randzio, J.-P. E. Grolier, and J. R. Quint,Fluid Phase Equil. (in press).
L. Ter Minassian, Ph. Pruzan, and A. Soulard,J. Chem. Phys. 75:3064 (1981).
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Randzio, S.L., Lewis, E.A., Eatough, D.J. et al. Thermophysical properties ofm-cresol as a function of temperture (303 to 503 K) and pressure (0.1 to 400 MPa). Int J Thermophys 16, 883–900 (1995). https://doi.org/10.1007/BF02093471
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DOI: https://doi.org/10.1007/BF02093471