Skip to main content
Log in

Electrochemical induction of alkali-silica reaction in concrete

  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

The use of cathodic protection as a method of countering chloride-induced corrosion of steel in concrete causes the formation of hydroxyl ions at the surface of the embedded metal. The preliminary experiments described in this note were aimed at evaluating a possible side-effect of this process under circumstances where the concrete contains a potentially reactive aggregate. For concrete specimens containing calcined flint aggregate, it was shown that deleterious local expansion of the material was generated owing to alkali-silica reaction induced in the vicinity of embedded steel when the latter was subjected to potentiostatic polarization for a period of several months at −850 mV (SCE scale). Continuing investigations are aimed at providing further insight into this phenomenon to aid the assessment of its practical implications.

Resume

L’utilisation de la protection cathodique pour neutraliser la corrosion de l’acier dans le béton provoquée par le chlorure entraîne la formation d’ions hydroxyles à la surface du métal enrobé. Les essais préliminaires décrits dans cette note avaient pour but d’évaluer un éventuel effet secondaire de ce processus dans les cas où le béton contient un granulat réactif. Pour les échantillons de béton contenant un granulat de silex calciné, on a montré que l’expansion locale nocive du matériau était provoquée par la réaction silicoalcaline qui se produit dans le voisinage de l’acier enrobé quand celui-ci est soumis à une polarisation potentiostatique pendant une durée de plusieurs mois à −850 mV (échelle SCE). Des études se poursuivent dans le but d’obtenir une connaissance plus approfondie de ce phénomène et contribuer à l’évaluation de ses conséquences pratiques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Strategic Highway Research Program, ‘Concrete and Structures: Progress and Products Update’ (National Research Council, Washington, DC, 1989).

    Google Scholar 

  2. Wallbank, E. J., ‘The Performance of Concrete in Bridges’ (HMSO, London, 1989).

    Google Scholar 

  3. Page, C. L. and Treadaway, K. W. J. ‘Aspects of the electrochemistry of steel in concrete’,Nature 297 (1982) 109–115.

    Article  Google Scholar 

  4. Manning, D. G., ‘Cathodic protection of concrete highway bridges’, in ‘Corrosion of Reinforcement in Concrete’, edited by C. L. Page, K. W. J. Treadaway and P. Bamforth (Elsevier Applied Science, London, 1990), pp. 486–497.

    Google Scholar 

  5. Hobbs, D. W., ‘Alkali-Silica Reaction in Concrete’, (Thomas Telford, London, 1988).

    Google Scholar 

  6. Diamond, S., ‘Alkali reactions in concrete-pore solution effects’ in ‘Alkalis in Concrete’, Proceedings of 6th International Conference, Copenhagen, 1983, edited by G. M. Idorn and S. Rostam (Danish Concrete Association. Copenhagen, 1983) pp. 155–156.

    Google Scholar 

  7. Nixon, P. and Page, C. L., ‘Pore solution chemistry and alkali aggregate reaction’,Amer. Concr. Inst. SP-100 (1987) 1833–1862.

    Google Scholar 

  8. Natesaiyer, K. and Hover, K. C., ‘Investigation of electrical effects on alkali-aggregate reaction’, in ‘Concrete Alkali-Aggregate Reactions’, Proceedings of 7th International Conference, Ottawa, 1986, edited by P. E. Grattan-Bellew (Noyes, New Jersey, 1987) pp. 466–471.

    Google Scholar 

  9. Lumley, J. S., ‘Synthetic cristobalite as a reference reactive aggregate’, in ‘Alkali-Aggregate Reaction’, Proceedings of 8th International Conference, Kyoto, 1989, edited by K. Okada, S. Nishibayashi and M. Kawamura (Elsevier Applied Science, London, 1989) pp. 561–566.

    Google Scholar 

  10. Concrete Society Technical Report No. 36, ‘Cathodic Protection of Steel in Concrete’ (The Concrete Society, London, 1989).

  11. Hunkeler, F. ‘Technical Report on Cathodic Protection Trial in San Bernardino Tunnel’ (Swiss Society for Corrosion Protection/Corrosion Commission, Zurich, 1989).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Crown Copyright. The views expressed in this paper are not necessarily those of the Department of Transport.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sergi, G., Page, C.L. & Thompson, D.M. Electrochemical induction of alkali-silica reaction in concrete. Materials and Structures 24, 359–361 (1991). https://doi.org/10.1007/BF02472069

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02472069

Keywords

Navigation