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Tetrazoles as ligands, part III. Transition metal complexes of 1-alkyltetrazoles

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Summary

Transition metal(II) tetrafluoroborates react with 1-alkyltetrazoles to give complexes with six ligands per metal ion,viz.; ML6(BF4)2 with M2+ = Mn2+, Co2+, Ni2+, Cu2+ or Zn2+ and L =1-methyltetrazole (MTz), 1-ethyltetrazole (ETz) and 1-propyltetrazole (PTz). The complexes were identified and characterized by chemical analyses, i.r. and ligand field spectra. They are apparently mononuclear, containing monodentate ligands for which the Dq values are exceptionally high.

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Authors and Affiliations

  1. Department of Coordination Chemistry, Gorlaeus Laboratoria, Rijksuniversiteit Leiden, P. O. Box 9502, 2300, RA Leiden, The Netherlands

    Peter L. Franke & Willem L. Groeneveld

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  1. Peter L. Franke
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  2. Willem L. Groeneveld
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Franke, P.L., Groeneveld, W.L. Tetrazoles as ligands, part III. Transition metal complexes of 1-alkyltetrazoles. Transition Met Chem 6, 54–56 (1981). https://doi.org/10.1007/BF01143471

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