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Complexes of cobalt(II), nickel(II) and copper(II) with 4-amino-3,5-dimethylisoxazole

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Summary

Complexes of the type M(4-ADI)nX2 · mH2O (where 4-ADI = 4-amino-3,5-dimethylisoxazole; n = 1–4; X = Cl, Br, I, SCN, ClO4; m = 1–4) have been studied by i.r. and electronic spectroscopy, magnetic and conductivity measurements. The ligand behaves as a monodentate -NH2 bonded species in monomeric complexes, but as a bridging ligand-NH2 and -N(ring) bonded species in polymeric complexes. All the compounds have an octahedral stereochemistry, except Co(4-ADI)2X2 (X = Cl, Br, I) complexes, which are tetrahedral.

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Authors and Affiliations

  1. Istituto Chimico Policattedra, Università di Cagliari, Via Ospedale 72, 09100, Cagliari, Italy

    Marco Biddau, Marcella Massacesi, Rosalba Pinna & Gustavo Ponticelli

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  1. Marco Biddau
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  2. Marcella Massacesi
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  3. Rosalba Pinna
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  4. Gustavo Ponticelli
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Biddau, M., Massacesi, M., Pinna, R. et al. Complexes of cobalt(II), nickel(II) and copper(II) with 4-amino-3,5-dimethylisoxazole. Transition Met Chem 3, 153–156 (1978). https://doi.org/10.1007/BF01393533

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  • DOI: https://doi.org/10.1007/BF01393533

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